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14712

Effect of Gamma irradiation on mechanical behavior of EPDM rubber-recycled news print microfibers composites

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Last updated: 03 Jan 2025

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Abstract

The waste newsprint paperswere collected from local market  and submitted to chemical pulping in a kneader with 2M NaOH. The fiber after getting rid of water, treated again using 2M HCL solution for the same time period. Then the news print pulped microfibers (NPMF) batch obtained was mixed with Ethylene propylene diene monomer rubber (EPDM) on roll mill with differnet contents ranged from 5 to 50phr (part per hundred part of rubber). The prepared composites subjected to gamma irradiation at different doses from 20 up to 100kGy. The characterization of the microfibers carried out by different tools like scanning electron microscopy (SEM), X-ray diffraction (XRD),Forrier Transform Infrared spectra (FTIR) and Thermogravimetric analysis (TGA). The mechanical properties of prepared composites like tensile strength (Ts), Elongation at break (Eb%), tensile modulus(M100) , tensile toughness and crosslink density (Cd) were measured as a function of fiber contents and irrdaition dose. The results indicated the Ts was increased with increasing fiber content up to 10phr and incresed with increasing irradiation dose up to 40kGy, while Eb% decreased by fiber content and irradiation dose. M100 and Cd were incresed with invreasing fiber content up 50phr fiber and increased by irradiation dose up to 60kGy. The results concluded that toughness values of EPDM/ news print fiber composite reach maximum using 10phr fiber concentration and 60kGy irradiation dose.  

DOI

10.21608/jsrs.2018.14712

Keywords

waste newsprint microfibers (NPMF)- EPDM/news print fiber composites Chemical repulping, Thermogravimetric analysis (TGA), X-ray difrraction (XRD), FTIR analysis– Mechanical properties

Authors

First Name

Magdy

Last Name

Ali

MiddleName

A. M.

Affiliation

Radiation Chemistry Department, National Center for Radiation Research and Technology, B.O. Box 29 Nasr City, Egyptian Atomic Energy Authority, Cairo Egypt

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City

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Orcid

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First Name

Khaled

Last Name

El-Nemr

MiddleName

F.

Affiliation

Radiation Chemistry Department, National Center for Radiation Research and Technology, B.O. Box 29 Nasr City, Egyptian Atomic Energy Authority, Cairo Egypt

Email

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City

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Orcid

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First Name

Amina

Last Name

Hamada

MiddleName

A.

Affiliation

AlAzhar University, Faculty of Sceince (Girls branch), Chemistry department

Email

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City

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Orcid

-

First Name

Wafaa

Last Name

Abd-elhady

MiddleName

S.

Affiliation

AlAzhar University, Faculty of Sceince (Girls branch), Chemistry department

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City

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Orcid

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Volume

34

Article Issue

part1

Related Issue

2422

Issue Date

2017-09-01

Receive Date

2018-09-25

Publish Date

2017-09-01

Page Start

333

Page End

359

Print ISSN

2356-8364

Online ISSN

2356-8372

Link

https://jsrs.journals.ekb.eg/article_14712.html

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https://jsrs.journals.ekb.eg/service?article_code=14712

Order

39

Type

Original Article

Type Code

656

Publication Type

Journal

Publication Title

Journal of Scientific Research in Science

Publication Link

https://jsrs.journals.ekb.eg/

MainTitle

Effect of Gamma irradiation on mechanical behavior of EPDM rubber-recycled news print microfibers composites

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Article

Created At

22 Jan 2023