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277040

Burghul Plant Extract as a Green Corrosion Inhibitor for Carbon Steel in Hydrochloric Acid Solution

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Last updated: 22 Jan 2023

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Abstract

Carbon steel is very important because it is widely used in many industrial and engineering fields, such as oil and gas. However, engineering materials accounted for 85% of yearly steel production due to their accessibility and affordability. As a result of strict environmental rules and a growing ecological consciousness among scientists, "green" ways to minimize corrosion have been created. In the current study, burghul extract is demonstrated to be an effective corrosion inhibitor and was utilized as an environmentally acceptable anti-corrosive material for carbon steel in a 1M HCl solution. The effectiveness of mitigation methods such as mass loss, electrochemical impedance spectroscopy, frequency modulation, and potentiodynamic polarization (PP) was calculated. Meanwhile, dispersion X-ray (EDX) and scanning electron microscopy (SEM) methods were used to analyze surfaces. Results obtained showed that temperature and extract concentration both affect how effective the mitigation is. The inhibition is attributed to the development of a protective layer that slows the dissolution of carbon steel at its surface. The Langmuir model was validated by the adsorption of burghul extract on steel. The adsorption of the extract affected both anodic and cathodic reactions. Tafel curves showed that burghul is a mixed inhibitor. The Nyquist curves confirmed that the burghul extract prevents the disintegration of steel in acidic media without changing the dissolution reaction mechanism. By using ATR-FTIR analysis and SEM inspection, the  burghul extract's adsorption on the metal carbon steel was verified. A maximum inhibitory efficacy of 95% was reached at 313 K using 300 ppm of the Burghul extract, which is thought to be a promising result.    

DOI

10.21608/cat.2022.277040

Keywords

Keywords: Burghul extract, carbon steel, Corrosion, Green Corrosion Inhibitors, plant extract

Authors

First Name

Medhat

Last Name

Kamel

MiddleName

M.

Affiliation

Department of Chemistry, Faculty of Science, Suez Canal University, Ismailia, Egypt

Email

madhat_kamel@yahoo.com

City

-

Orcid

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First Name

Abdel Aziz

Last Name

Fouda

MiddleName

S.

Affiliation

Department of Chemistry, Faculty of Science, Mansoura University, El-Mansoura, Egypt

Email

-

City

Mansoura

Orcid

-

First Name

Salah

Last Name

Rashwan

MiddleName

M.

Affiliation

Department of Chemistry, Faculty of Science, Suez Canal University, Ismailia, Egypt

Email

-

City

Ismailia

Orcid

-

First Name

Osama

Last Name

Marei

MiddleName

Abdelkader

Affiliation

Department Of Chemistry Faculty Of Science Suez Canal University

Email

os.abdelkader@gmail.com

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-

Orcid

-

Volume

26

Article Issue

1

Related Issue

38230

Issue Date

2022-12-01

Receive Date

2022-09-20

Publish Date

2022-12-01

Page Start

19

Page End

31

Print ISSN

1687-5052

Online ISSN

2090-2786

Link

https://cat.journals.ekb.eg/article_277040.html

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https://cat.journals.ekb.eg/service?article_code=277040

Order

277,040

Type

Original Article

Type Code

644

Publication Type

Journal

Publication Title

Catrina: The International Journal of Environmental Sciences

Publication Link

https://cat.journals.ekb.eg/

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Article

Created At

22 Jan 2023