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15557

Synthesis and Characterization of Bis-azo 1,2,4,5-Tetrazine Dyestuff

Article

Last updated: 03 Jan 2025

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Abstract

The design, synthesis and characterization of symmetrical 3,6-Bis(2-(4-(dodecyloxy)phenyl)-1-(4-(phenyl)diazene)-1,2,4,5-tetrazine are described. The novel sym-tetrazine was prepared by addition reaction of 4-(2-(4-decyloxyphenyl)diazenyl)benzonitrile with hydrazine monohydrate followed by oxidation reaction to afford the corresponding bis(azo)-1,2,4,5-tetrazine. The chemical structure of the sym-tetrazine compound was confirmed by elemental analysis, fourier-transform infrared spectroscopy (FT-IR), and nuclear magnetic resonance (1H and 13C NMR) spectral measurements.
The design, synthesis and characterization of symmetrical 3,6-Bis(2-(4-(dodecyloxy)phenyl)-1-(4-(phenyl)diazene)-1,2,4,5-tetrazine are described. The novel sym-tetrazine was prepared by addition reaction of 4-(2-(4-decyloxyphenyl)diazenyl)benzonitrile with hydrazine monohydrate followed by oxidation reaction to afford the corresponding bis(azo)-1,2,4,5-tetrazine. The chemical structure of the sym-tetrazine compound was confirmed by elemental analysis, fourier-transform infrared spectroscopy (FT-IR), and nuclear magnetic resonance (1H and 13C NMR) spectral measurements.

DOI

10.21608/jtcps.2018.5033.1003

Keywords

sym-Tetrazine, Bis-azo, Disperse dye

Authors

First Name

Tawfik

Last Name

Khattab

MiddleName

A.

Affiliation

National Research Centre

Email

tkhattab@kent.edu

City

Cairo

Orcid

0000-0001-7834-4952

First Name

Mohamed

Last Name

Rehan

MiddleName

-

Affiliation

National Research Centre

Email

rehan_nrc@yahoo.com

City

Cairo

Orcid

-

Volume

15

Article Issue

1

Related Issue

4919

Issue Date

2018-12-01

Receive Date

2018-09-04

Publish Date

2018-12-01

Page Start

33

Page End

36

Print ISSN

2682-2024

Online ISSN

2682-1958

Link

https://jtcps.journals.ekb.eg/article_15557.html

Detail API

https://jtcps.journals.ekb.eg/service?article_code=15557

Order

3

Type

Original Article

Type Code

615

Publication Type

Journal

Publication Title

Journal of Textiles, Coloration and Polymer Science

Publication Link

https://jtcps.journals.ekb.eg/

MainTitle

Synthesis and Characterization of Bis-azo 1,2,4,5-Tetrazine Dyestuff

Details

Type

Article

Created At

22 Jan 2023