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7271

A SCIENTIFIC STUDY OF THE PATINA, CORROSION MORPHOLOGY, AND CONSERVATION OF EGYPTIAN BRASS OBJECT

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Last updated: 22 Jan 2023

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Abstract

This paper presents the way we used non-destructive methods-optical microscopy (OM),
scanning electron microscopy (SEM) coupled with energy dispersive X-ray analysis (EDX), xray
diffraction (XRD) and Fourier-transform Raman (FT-Raman) microscopy. The Raman
spectra of copper were reported using an Nd-YAG laser operating at an excitation wavelength
of 1064, 785and532 nm. These analyses were used to understand the corrosive
morphological characteristics of the patina, to investigate the corrosion products, analyze the
elementary composition of the copper object and to identify the corrosive factors with effects
on the alteration processes. This object exhibited at the museum of the faculty of applied arts,
Helwan university-Egypt. The results indicated that the object was made of brass alloy, with
copper as the main element, beside zinc. Three layers of alteration products with various
composition and morphology covered the substrate of the brass alloy. SEM-EDX, XRD
analyses and Raman spectroscopy (RS) revealed the elements Cl, S, O, C, from primary and
secondary chemical compounds and from soil micro-structure. This study provides useful
information for the conservation of copper object.

DOI

10.21608/ejars.2018.7271

Keywords

Copper corrosion, minerals, Patina, Raman spectroscopy (RS), Brass treatment

Authors

First Name

Gharib

Last Name

A.

MiddleName

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Affiliation

Lecturer Conservation dept., Faculty of Fine Arts, Minia Univ., Minia, Egypt

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Volume

4

Article Issue

1

Related Issue

1374

Issue Date

2014-06-01

Receive Date

2018-05-15

Publish Date

2014-06-01

Page Start

25

Page End

33

Print ISSN

2090-4932

Online ISSN

2090-4940

Link

https://ejars.journals.ekb.eg/article_7271.html

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https://ejars.journals.ekb.eg/service?article_code=7271

Order

3

Type

Original Article

Type Code

575

Publication Type

Journal

Publication Title

Egyptian Journal of Archaeological and Restoration Studies

Publication Link

https://ejars.journals.ekb.eg/

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Article

Created At

22 Jan 2023