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22606

SPECTRAL STUDY FOR THE EFFECT OF SOLVENT DIELECTRIC CONSTANT ON THE OPTICAL BAND GAP FOR (4-OXOTHIAZOLIDIN-2-YLIDENE) ACETONITRILE.

Article

Last updated: 03 Jan 2025

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Tags

Physics

Abstract

Heterocyclic compound of (4-oxothiazolidin-2-ylidene) acetonitrile was prepared in powder form. The crystalline
nature of the prepared sample was checked by X- ray diffraction (XRD). IR absorption spectra were recorded on a
Shimadzu 440 infrared spectrophotometer (cm-1) using the KBr technique (Shimadzu, Japan). Reflection spectra
of the powder sample were obtained in the wavelength range (200-2500 nm) at room temperature using spectrophotometer.
Absorption and transmission spectra of the prepared sample were obtained in different solvents in
the wavelength range (190-1100nm).The solvent used are acetone, dimethyformamid (D.M.F.) and glycerol. The
measurements were carried out at room temperature using (JENWAY 6405 UV/VIS) spectrophotometer. The optical
energy gap which is the difference between lowest unoccupied molecular orbital (LUMO) and highest occupied
molecular orbital (HOMO) was estimated. The effect of the solvent dielectric constant on optical band gap was
discussed. 

DOI

10.21608/absb.2014.22606

Keywords

Optical band gap, FT-IR absorption and X-ray diffraction

Authors

First Name

M.

Last Name

Ibrahim

MiddleName

-

Affiliation

Departments of Physics , Faculty of Science, Al Azhar University, Nasr city, Cairo 11884, Egypt.

Email

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City

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Orcid

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First Name

G. A. M.

Last Name

El Hag Ali

MiddleName

-

Affiliation

Chemistry, Faculty of Science, Al Azhar University, Nasr city, Cairo11884, Egypt

Email

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City

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Orcid

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Volume

25

Article Issue

Issue 2-B

Related Issue

4289

Issue Date

2014-12-01

Receive Date

2014-08-07

Publish Date

2014-12-01

Page Start

15

Page End

19

Print ISSN

1110-2535

Online ISSN

2636-3305

Link

https://absb.journals.ekb.eg/article_22606.html

Detail API

https://absb.journals.ekb.eg/service?article_code=22606

Order

3

Type

Original Article

Type Code

520

Publication Type

Journal

Publication Title

Al-Azhar Bulletin of Science

Publication Link

https://absb.journals.ekb.eg/

MainTitle

SPECTRAL STUDY FOR THE EFFECT OF SOLVENT DIELECTRIC CONSTANT ON THE OPTICAL BAND GAP FOR (4-OXOTHIAZOLIDIN-2-YLIDENE) ACETONITRILE.

Details

Type

Article

Created At

22 Jan 2023