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10043

EFFECT OF ADDITION OF SOME ORGANIC AND INORGANIC COMPOUNDS ON THE PITTING CORROSION OF STAINLESS STEEL ELECTRODES

Article

Last updated: 03 Jan 2025

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Tags

Chemistry

Abstract

The corrosion behavior of two stainless steel electrodes with different chemical compositions in different salt solutions of Cl¯ ions (NaCl, FeCl3 and HgCl2) was studied.  The corrosion behavior in 3.5% NaCl with and without different concentrations of two different triazole derivatives, 3-amino-1, 2, 4 triazole (AT) and 4-amino-5-mercapto-1, 2, 4 triazole (AMT) and Na2S2O3 ­(50 to 200ppm.) was studied.  Open circuit potential measurements, potentiodynamic cyclic anodic polarization (PCAP) and surface morphology techniques were used in this study. Obtained results showed that NaCl is more aggressive comparing with FeCl3 and HgCl2. As the concentration of sodium chloride increased, the (PCAP) curves indicated the presence of pitting or crevice corrosion breakdown potential which sustained the increase of anodic current density. The plots of pitting potential (Epit.), or protection potential (Ep) versus log [Cl¯] at 25oC, for the two stainless steel electrodes were linearly decreased with the increase of the logarithm of chloride concentration. Also the increase of scan rate increases the localized pitting corrosion. The additions of sodium thiosulphate to 3.5% NaCl enhance pitting corrosion as compared with that found in pure sodium chloride solution. On the contrary, increasing concentration of (AT) and (AMT) in NaCl solution was found to greatly enhance IE%. The adsorptive behavior of the investigated inhibitors on the steel surface followed Langmiur-type isotherm. These results indicate the suitability of the use of the investigated inhibitors.  Electrode type (I) has a greater tendency for pitting than electrode type (II) due to the percentage of nickel in electrode type (I) is half that of electrode type (II).

DOI

10.21608/absb.2008.10043

Keywords

ORGANIC AND INORGANIC, PITTING CORROSION, STAINLESS STEEL ELECTRODES

Authors

First Name

A.

Last Name

AHMED

MiddleName

S.

Affiliation

Chemistry Department, Faculty of Science (for Girls), Al-Azhar University, Nasr City, Cairo, Egypt

Email

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City

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Orcid

-

First Name

R.

Last Name

ABOU SHAHBA

MiddleName

M.

Affiliation

Chemistry Department, Faculty of Science (for Girls), Al-Azhar University, Nasr City, Cairo, Egypt

Email

-

City

-

Orcid

-

First Name

E.

Last Name

ATTIA

MiddleName

M.

Affiliation

Chemistry Department, Faculty of Science (for Girls), Al-Azhar University, Nasr City, Cairo, Egypt

Email

-

City

-

Orcid

-

First Name

IBRAHIME

Last Name

GHAYAD

MiddleName

M.

Affiliation

Central metallurgical research and development institute, Cairo, Egypt.

Email

-

City

-

Orcid

-

First Name

W.

Last Name

HUSSEIN

MiddleName

A.

Affiliation

Chemistry Department, Faculty of Science (for Girls), Al-Azhar University, Nasr City, Cairo, Egypt

Email

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City

-

Orcid

-

Volume

19

Article Issue

Issue 1-A

Related Issue

1639

Issue Date

2008-06-01

Receive Date

2008-01-27

Publish Date

2008-06-01

Page Start

309

Page End

335

Print ISSN

1110-2535

Online ISSN

2636-3305

Link

https://absb.journals.ekb.eg/article_10043.html

Detail API

https://absb.journals.ekb.eg/service?article_code=10043

Order

21

Type

Original Article

Type Code

520

Publication Type

Journal

Publication Title

Al-Azhar Bulletin of Science

Publication Link

https://absb.journals.ekb.eg/

MainTitle

EFFECT OF ADDITION OF SOME ORGANIC AND INORGANIC COMPOUNDS ON THE PITTING CORROSION OF STAINLESS STEEL ELECTRODES

Details

Type

Article

Created At

22 Jan 2023