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7349

KINETICS AND MECHANISM OF OXIDATION OF P-ANISIDINE BY FE(III) SOLUTION IN ACIDIC MEDIUM

Article

Last updated: 03 Jan 2025

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Tags

Chemistry

Abstract

Kinetics of oxidation of p-anisidine by Fe(III) ion was studied spectrophotometry in acidic medium. The rate constant was found to increase with increasing p-anisidine and hydrogen ion concentrations. The order of reaction was found to be first order with respect to both Fe(III) ion and p-anisidine concentration. The suggested mechanism involves the interaction of the reactive species of the reactants to form the activated complex which decompose in a rate determining step to products. The rate law was derived and activation parameters are calculated to be ļ„H* = 47 kJ mol-1 and ļ„S* = -148.6 JK-1 mol-1

DOI

10.21608/absb.2010.7349

Keywords

P-anisidine, FE(III)

Authors

First Name

MOHAMED

Last Name

MANSOUR

MiddleName

A.

Affiliation

Chemistry Department, Faculty of Science, Ain Shams University, Abbassia, Cairo, Egypt

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City

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Volume

21

Article Issue

Issue 1-A

Related Issue

1398

Issue Date

2010-06-01

Receive Date

2010-01-14

Publish Date

2010-06-01

Page Start

209

Page End

216

Print ISSN

1110-2535

Online ISSN

2636-3305

Article File

ABSB_Volume 21_Issue Issue 1-A_Pages 209-216.pdf

PDF . 535.5kB

Link

https://absb.journals.ekb.eg/article_7349.html

Detail API

https://absb.journals.ekb.eg/service?article_code=7349

Order

15

Type

Original Article

Type Code

520

Publication Type

Journal

Publication Title

Al-Azhar Bulletin of Science

Publication Link

https://absb.journals.ekb.eg/

MainTitle

KINETICS AND MECHANISM OF OXIDATION OF P-ANISIDINE BY FE(III) SOLUTION IN ACIDIC MEDIUM

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Article

Created At

22 Jan 2023