7343

REMOVAL OF HEAVY METAL IONS FROM CONTAMINATED WATER USING CORNCOB-SULPHONATED PHENOL FORMALDEHYDE CONDENSATE

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Last updated: 03 Jan 2025

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Chemistry

Abstract

This paper is focused on the use of agricultural by-product as a replacement of the running low cost method for removing heavy toxic and/or radioactive metal ions from water and wastewater. The modification of Egyptian corncobs as a source of low cost plant and recycling material with phenol has been developed in presence of para-formaldedhyde as a cross linking agent. The modification of corncobs was investigated to enhance their natural capacity and could be considered as an added value to the waste plant. In this study, the characterization of the synthesized sulphonated corncob–phenol formaldehyde exchange resin is described and compared with the Dowex HYRW2 –Na polisher cation exchanger. It was found that the synthesized resin is stable in hot water (100oC), mineral acids (2M), in all most common solvents, and alkali solutions 1:0M withstand temperature up to 100oC. The modified corncob resin has an exchange capacity of 2.84 m.eq. /g dry resin –H+ form. The character of copolymer resin adsorption efficiency towards heavy toxic metals has been investigated via different concentrations of Mg (II), Mn (II), Fe (III), Cu (II), Zn (II), Cd (II) and Pb (II) individually in pure aqueous water and aqueous– HCl solutions. Finally a comparison of their removal performance with that of the commercial and the prepared resins was presented in this study where as the last one showed good adsorption efficiency.

DOI

10.21608/absb.2010.7343

Keywords

Corncob, phenol formaldehyde resin, removal of toxic elements by low cost materials, Ion exchange separation

Authors

First Name

ABDUL–ALEEM

Last Name

ABOUL–MAGD

MiddleName

S.

Affiliation

Faculty of Science, Al–Azhar University Department of Chemistry, Cairo, Egypt

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City

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Orcid

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First Name

SALWA

Last Name

EL–RASHED

MiddleName

H.

Affiliation

Faculty of Education, Chemistry Department, King Abdul–Aziz Jeddah, K.S.A

Email

-

City

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Orcid

-

First Name

SALMA

Last Name

AL–ZAHRANI

MiddleName

A.

Affiliation

Faculty of Science, Chemistry Department, Hail University, Hail, K.S.A

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-

City

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Orcid

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Volume

21

Article Issue

Issue 1-A

Related Issue

1398

Issue Date

2010-06-01

Receive Date

2010-01-02

Publish Date

2010-06-01

Page Start

161

Page End

174

Print ISSN

1110-2535

Online ISSN

2636-3305

Link

https://absb.journals.ekb.eg/article_7343.html

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https://absb.journals.ekb.eg/service?article_code=7343

Order

11

Type

Original Article

Type Code

520

Publication Type

Journal

Publication Title

Al-Azhar Bulletin of Science

Publication Link

https://absb.journals.ekb.eg/

MainTitle

REMOVAL OF HEAVY METAL IONS FROM CONTAMINATED WATER USING CORNCOB-SULPHONATED PHENOL FORMALDEHYDE CONDENSATE

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Article

Created At

22 Jan 2023