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7027

COMPARATIVE STUDY BETWEEN HIGH PERFORMANCE LIQUID CHROMATOGRAPHY AND GAS CHROMATOGRAPHY FOR DETERMINATION OF BISPHENOL A IN THE BABY BOTTLES

Article

Last updated: 03 Jan 2025

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Tags

Chemistry

Abstract

In this study, bisphenol A (BPA), the migrant from the polycarbonate baby bottles was determined using high performance liquid chromatograph (HPLC) with both detectors, (fluorescence, FLU and UV) and gas chromatograph with mass spectrophotometer detector (GC/MS). The results exhibited a noticable variation in the amounts of BPA measured by HPLC using both FLU and UV detectors at the same condition. However, this variation was more pronounced between the results of HPLC/FLU analyses and the corresponding ones for the same sample at GC/MS. Since, the BPA levels in the HPLC analyses were lower than those in the GC/MS analyses. Meanwhile, the detection limit of BPA was broader for the HPLC method comparing with that for GC/MS method. These differences in measured BPA levels for both two chromatographic methods may result mainly from low sensitivity noticed in HPLC method, particularly, at lower BPA levels and relatively poor resolution at higher BPA levels. This is due to the great varied sensitivity between the two instruments (HPLC)& (GC/MS) and between the two detectors of HPLC (FLU&UV). However, there was no report, which simultaneously evaluated the two methods in real analyses. We found that there were strong variation between BPA levels in the baby bottles samples with the two methods, for this we recommended the GC/MS for The BPA detection method.

DOI

10.21608/absb.2011.7027

Keywords

Bisphenol A-Polycarbonate, Migration Baby bottles, HPLC–GC/MS

Authors

First Name

E.

Last Name

SOLIMAN

MiddleName

A.

Affiliation

Department of Polymer Materials Research, Advanced Technology and New Materials Research Institute, CSRTA, New Borg El-Arab, 21934, Alexandria, Egypt.

Email

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City

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Orcid

-

First Name

A.

Last Name

MOSTAFA

MiddleName

H.

Affiliation

Department of Chemistry, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt.

Email

-

City

-

Orcid

-

First Name

M.

Last Name

MOHY EL-DIN

MiddleName

S.

Affiliation

Department of Polymer Materials Research, Advanced Technology and New Materials Research Institute, CSRTA, New Borg El-Arab, 21934, Alexandria, Egypt.

Email

-

City

-

Orcid

-

First Name

G.

Last Name

ABD EL-NAEEM

MiddleName

-

Affiliation

Department of Polymer Materials Research, Advanced Technology and New Materials Research Institute, CSRTA, New Borg El-Arab, 21934, Alexandria, Egypt.

Email

-

City

-

Orcid

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Volume

22

Article Issue

Issue 2-A

Related Issue

1329

Issue Date

2011-12-01

Receive Date

2011-07-03

Publish Date

2011-12-01

Page Start

193

Page End

204

Print ISSN

1110-2535

Online ISSN

2636-3305

Link

https://absb.journals.ekb.eg/article_7027.html

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https://absb.journals.ekb.eg/service?article_code=7027

Order

16

Type

Original Article

Type Code

520

Publication Type

Journal

Publication Title

Al-Azhar Bulletin of Science

Publication Link

https://absb.journals.ekb.eg/

MainTitle

COMPARATIVE STUDY BETWEEN HIGH PERFORMANCE LIQUID CHROMATOGRAPHY AND GAS CHROMATOGRAPHY FOR DETERMINATION OF BISPHENOL A IN THE BABY BOTTLES

Details

Type

Article

Created At

22 Jan 2023