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HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF NANO SIZED ZSM-5 AND THEIR EFFECT ON THE DECOLORIZATION OF INDIGO CARMINE DYE

Article

Last updated: 03 Jan 2025

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-

Tags

Chemistry

Abstract

Silica sources can influence different effects of ZSM-5 crystallization and it leads to change in the properties of the final product. The crystallinity of nanosized ZSM-5 zeolite from precursors mixtures containing different silica sources, e.g. tetraethylorthosilicate (TEOS), colloidal silica (CS), silicic acid(SA) and fumed silica(FS) have been studied. The produced samples are investigated using XRD, SEM, FT-IR, pyridine adsorption and N2 adsorption measurements. XRD results show that the product obtained by different silica sources is nano sized ZSM-5 phase. SEM results show that silica sources influences on shape of the produced ZSM-5; the sample which was prepared by silicic acid crystallized in spherical shape crystals, the samples which was prepared by TEOS crystallized in cubical shape crystals, the sample which was prepared by colloidal silica crystallized in spherical shape crystals with smaller aggregated but the sample which was prepared by fumed silica crystallized in round shape crystals. N2 adsorption results show thatsilica sources influences on pore diameter and pore volume of the produced ZSM-5.The adsorption of indigo carmine dye by ZSM-5 has been studied. It was found that the synthesized zeolite by SA exhibited significantly higher adsorption capacity for indigo carmine than other ZSM-5 states due to the difference in morphological properties. The optimum ZSM-5 loading is 1 g at pH 4 after 180 min.

DOI

10.21608/absb.2013.6407

Keywords

HYDROTHERMAL SYNTHESIS, NANO ZSM-5, Dye decolorization

Authors

First Name

IBRAHEEM

Last Name

Ali

MiddleName

O.

Affiliation

Department of Chemistry, Faculty of Science, Al-Azhar University, Cairo, Egypt

Email

ibraheem_othman2002@yahoo.com

City

-

Orcid

-

First Name

IBRAHEM

Last Name

IBRAHEM

MiddleName

A.

Affiliation

Department of Chemistry, Faculty of Science, Al-Azhar University, Cairo, Egypt

Email

-

City

-

Orcid

-

First Name

KARAM

Last Name

ELNASSER

MiddleName

S.

Affiliation

Department of Chemistry, Faculty of Science, Al-Azhar University, Cairo, Egypt

Email

-

City

-

Orcid

-

Volume

24

Article Issue

Issue 2-A

Related Issue

1105

Issue Date

2013-12-01

Receive Date

2013-09-04

Publish Date

2013-12-01

Page Start

37

Page End

52

Print ISSN

1110-2535

Online ISSN

2636-3305

Link

https://absb.journals.ekb.eg/article_6407.html

Detail API

https://absb.journals.ekb.eg/service?article_code=6407

Order

3

Type

Original Article

Type Code

520

Publication Type

Journal

Publication Title

Al-Azhar Bulletin of Science

Publication Link

https://absb.journals.ekb.eg/

MainTitle

HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION OF NANO SIZED ZSM-5 AND THEIR EFFECT ON THE DECOLORIZATION OF INDIGO CARMINE DYE

Details

Type

Article

Created At

22 Jan 2023