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76430

Efficient Removal of the Toxic Lead Ions from ContaminatedSandy Soils using Newly Engineered Carbon Black Nanoadsorbent

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Last updated: 22 Jan 2023

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Abstract

Soils contaminated with heavy metals can embarrass a fatal risk to the environment and human life via the direct uptake of the heavy metal-contaminated agricultural crops. Hence, the treatment of metal-contaminated soils is attracting a lot of research activities to reduce the negative impact on the environment. In the current study, I have activated the surface of the carbon black (CB) adsorbent by introducing functional groups capable to efficiently capture the lead (Pb) metal ions from a Pb-contaminated sandy soil. The soil properties (e.g. electrical conductivity, acidity, carbon and nitrogen content, and organic matter) were studied before and after the treatment with the CB adsorbent. I also showed a comprehensive adsorption study in soil-batch extraction experiments, evaluating a series of factors such as the effects of soil pH (pH 3.0 to pH 7.0), Pb concentration into the soil (5-100 mg/L), and the soil temperature (15-50 °C).Furthermore, the recyclability of the adsorbent was highlighted to evaluate adsorption efficiency upon use. The results of the study were remarkable where a 100 % removal efficiency of Pb ions was obtained using only a 40 ppm of the oxidized CB compared to a 60% removal efficiency when using a pristine CB at the same concentration. The adsorption capacity of Pb ions was as high as 100 mg/g at 30 mg/L of oxidized CB adsorbent. The life cycle of oxidized CB adsorbent was also remarkable compared to that of pristine adsorbent. The recyclability data of the functionalized CB has showed an easy regeneration process with an efficient reusefor 5 cycles with 30 %a performance decline of 30 % only from the initial adsorption efficiency

DOI

10.21608/alexja.2019.76430

Authors

First Name

Inas

Last Name

H.Hafez

MiddleName

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Affiliation

Department of Natural resources and Agricultural Engineering, Faculty of Agriculture, Damanhour University, Damanhour 22516, Egypt.

Email

ihhafez@agr.dmu.edu.eg

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Volume

64

Article Issue

4

Related Issue

10759

Issue Date

2019-08-01

Receive Date

2020-03-08

Publish Date

2019-08-01

Page Start

257

Page End

267

Print ISSN

0044-7250

Online ISSN

2535-1931

Link

https://alexja.journals.ekb.eg/article_76430.html

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https://alexja.journals.ekb.eg/service?article_code=76430

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3

Type

Original Article

Type Code

514

Publication Type

Journal

Publication Title

Alexandria Journal of Agricultural Sciences

Publication Link

https://alexja.journals.ekb.eg/

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Article

Created At

22 Jan 2023