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20333

Phenol Adsorption from Simulated Wastewater on Rice Husk Activated Carbon and Granular Activated Carbon

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Last updated: 22 Jan 2023

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Abstract

Background: Phenol has been classified as hazardous pollutant and its presence in natural water is considered as a serious threat to human health and overall water quality.  The major source of phenol pollution in the aquatic environment is wastewater from petroleum and petrochemical industries. Objective: This study aims to investigate the adsorption efficiency of granular activated carbon (GAC) and activated carbon prepared from rice husk (RHAC), a low-cost agricultural by product, in removing phenols from simulated wastewater. Methods: Batch adsorption studies were conducted to study the effect of various parameters such as initial concentration, agitation time, adsorbent dose and solution pH on phenol removal. Equilibrium data were analyzed by the Langmuir, Freundlich, Temkin and Hurkin-Jura. The adsorption kinetics were studied using the pseudo-first-order and second-order kinetics models. The mechanism of the adsorption process was determined from the intraparticle diffusion model. Results:  The efficiency of GAC and RHAC on removal of phenol was 95% and 90% respectively at an agitation time of 6 hr, a pH 6,150 rpm, an adsorbent dose of 5 g/L, initial phenol concentration of 50 mg/L and a temperature of 20ºC. Acidic pH was more favorable for the removal of phenol.  Increasing initial concentration of phenol decreases the percentage removal. The adsorption isotherm models fitted the data in the order: Freundlich > Langmuir > Tempkin isotherms. The pseudo-second-order kinetic model best described the adsorption process Conclusion: The results showed that the prepared activated carbon was an effective adsorbent for removal of phenol as a low-cost and an alternative adsorbent.

DOI

10.21608/jhiph.2014.20333

Keywords

Adsorption, Phenol, Granular activated carbon, rice husk, Wastewater

Authors

First Name

Riham

Last Name

Ali Hazzaa

MiddleName

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Affiliation

Petrochemical Department, Faculty of Engineering, Pharos University in Alexandria, Egypt

Email

riham17@yahoo.com

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Orcid

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Volume

44

Article Issue

2

Related Issue

4064

Issue Date

2014-10-01

Receive Date

2018-12-03

Publish Date

2014-10-01

Page Start

77

Page End

87

Print ISSN

2357-0601

Online ISSN

2357-061X

Link

https://jhiphalexu.journals.ekb.eg/article_20333.html

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https://jhiphalexu.journals.ekb.eg/service?article_code=20333

Order

3

Type

Original Article

Type Code

511

Publication Type

Journal

Publication Title

Journal of High Institute of Public Health

Publication Link

https://jhiphalexu.journals.ekb.eg/

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Article

Created At

22 Jan 2023