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38046

The effect of the interface on magnetic properties of perovskite-spinel nanocomposites

Article

Last updated: 23 Dec 2024

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Abstract

In this research, perovskite-spinel nanocomposite with formula (x)(Cuo.3Mn0.7Fe2O4)- (1-x)(La0.9o Bi0.10 FeO3); 0 ≤ x ≤ 1, were prepared by the auto-combustion method. A single phase of orthorhombic and cubic structure for La0.9oBi0.10FeO3(LBFO); Cuo.3Mn0.7Fe2O4(CMFO) respectively have been proved for two parents and nanocomposites without any further secondary phase using XRD analysis. High-resolution transmission electron microscopy (HRTEM) images reveal nearly spherical nanoparticles for the parents and agglomerated for nanocomposites. Magnetic hysteresis loops demonstrate ferromagnetic (FM) behavior for the spinel compound and nanocomposite, where LBFO possesses G-type antiferromagnetic (AFM). Competition between FM and AFM phases lead to enhancement in magnetic parameters such as saturation magnetization (Ms), remnant magnetization (Mr) and coercivity (Hc). The magnetic properties at low temperatures show the decrease in magnetization and coercivity with increasing the temperature while the magnetic exchange bias HEB was increased until T=200 K and then decreased. The existence of intergranular magnetostatic interactions between the LBFO and CMFO interact at the interface of nanocomposites and play a decisive role in strain energy, exchange energy, and magnetic anisotropy

DOI

10.21608/ajnsa.2019.7827.1176

Keywords

Nanocomposites, perovskite-spinel, Magnetic properties, exchange interaction, exchange bias

Authors

First Name

E.

Last Name

El-Khawas

MiddleName

H.

Affiliation

Higher Technological Institute 10th of Ramadan city

Email

enash12@hotmail.com

City

Cairo

Orcid

-

Volume

52

Article Issue

3

Related Issue

6040

Issue Date

2019-07-01

Receive Date

2019-01-31

Publish Date

2019-07-01

Page Start

232

Page End

241

Print ISSN

1110-0451

Online ISSN

2090-4258

Link

https://ajnsa.journals.ekb.eg/article_38046.html

Detail API

https://ajnsa.journals.ekb.eg/service?article_code=38046

Order

23

Type

Original Article

Type Code

455

Publication Type

Journal

Publication Title

Arab Journal of Nuclear Sciences and Applications

Publication Link

https://ajnsa.journals.ekb.eg/

MainTitle

The effect of the interface on magnetic properties of perovskite-spinel nanocomposites

Details

Type

Article

Created At

22 Jan 2023