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267667

Cerium organic frameworks as green pollution preventing materials for dye removal

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Environmental chemistry

Abstract

Cerium organic frameworks are presented in this work as pollutant preventing materials for the removal of reactive red 195 dye (RR 195) from aqueous solutions. Anthranilic acid and β-diketone as ligand sources were used in the separate state for the preparation of the cerium complexes metal organic frameworks (MOF1- MOF2) with a stoichiometric ratio 1:2 The prepared MOFs were used as adsorbent materials for decontamination of coloured solutions.

The prepared materials were fully characterized by SEM, EDX, FTIR, surface area and zeta potential. The adsorption conditions (adsorption time, adsorbent loading, pH and dye concentration) were thoroughly optimized. The maximum adsorption capacity of the tertiary complex was more than that of the binary complexes. Different isothermal models (Langmuir, Freundlich, Temkin, and Dubinin–Kaganer–Radushkevich) have been studied. The physic-sorption adsorption of RR 195 behaviour is more fit to the Langmuir isotherm model through the pseudo-second-order kinetic model. That study introduces the promising cerium organic framework as pollution preventing material through dye removal.

DOI

10.21608/ejchem.2022.168639.7084

Keywords

Diketone, anthranilic acid, metal organic frameworks, Adsorption, Anionic dyes

Authors

First Name

Eman

Last Name

Mansor

MiddleName

Sobhy

Affiliation

National Research Center, Dokki, Cairo, Egypt

Email

eman_mansor31@yahoo.com

City

Cairo

Orcid

-

First Name

Tarek

Last Name

Aysha

MiddleName

-

Affiliation

Textile Research and Technology Institute, National Research Centre

Email

tarekaysha@hotmail.com

City

Cairo

Orcid

0000-0001-5632-1426

Volume

65

Article Issue

13

Related Issue

37459

Issue Date

2022-12-01

Receive Date

2022-10-13

Publish Date

2022-12-01

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_267667.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=267667

Order

267,667

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Cerium organic frameworks as green pollution preventing materials for dye removal

Details

Type

Article

Created At

22 Jan 2023