Beta
257263

Effect of increasing Fe-concentrations on ZnO thin film deposited by sol-gel spin coater.

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Material science

Abstract

To produce transparent thin films of undoped and Fe-loaded zinc oxide (ZnO) referred to as ZTF, Z (15-30 %F), the current study utilizes a modified sol-gel spin coating method (Zn-Fe). Both undoped and Fe-loaded ZnO thin films were annealed at 5000C for 2 hours. The morphologies and the structural characteristics of pure and doped ZnO thin films were studied. The structure of the resulting films was investigated using X-ray diffraction (XRD) spectra, revealing good crystal quality and a pure hexagonal wurtzite ZnO structure free of Fe-associated phases. The crystallite size of undoped ZnO thin film is 10.47 nm, and it decreases when the Fe content is increased to 25 mol. %, then it returns to increase at 30 mol. %, giving the following values 10.37, 9.66, 8.26, and 15.59 nm, respectively. Plane images were taken with a field emission scanning electron microscope (FESEM) revealing spherical particles and smooth surface shapes in the ZnO thin film, whilst Fe-loaded ZnO films have a uniform and compact morphology. The Laser-based Raman micro-spectroscopy presents the homogenous distribution of the iron oxide. The optical properties of thin films, such as transmittance (T %) and the absorption coefficient obtained from the absorbance spectrum were determined using UV/vis spectroscopy. The T% of ZTF film exhibited an average value of nearly 97% and reduced when the Fe concentrations were increased. ZTF, Z15FTF, Z20FTF, Z25FTF, and Z30FTF have energy band gaps of 3.138, 3.234, 3.240, 3.242, 2.936eV, respectively.

DOI

10.21608/ejchem.2022.155702.6724

Keywords

Sol – Gel, Thin film, ZnO, iron, 3-D laser Raman

Authors

First Name

Nora Y.

Last Name

Elsheikh

MiddleName

-

Affiliation

Menoufia University, Faculty of Electronic Engineering, Physics and Mathematical Engineering Department, 32952 Menouf, Egypt.

Email

-

City

-

Orcid

-

First Name

Inas

Last Name

Battisha

MiddleName

K.

Affiliation

National Research Centre, Solid state physics department, Physics Research Institute, Dokki, Giza, Egypt, Affiliation ID: 60014618

Email

szbasha5@yahoo.com

City

cairo

Orcid

-

First Name

Ahmed

Last Name

Abo Arais

MiddleName

-

Affiliation

Menoufia University, Faculty of Electronic Engineering, Physics and Mathematical Engineering Department, 32952 Menouf, Egypt.

Email

-

City

-

Orcid

-

First Name

M.S.

Last Name

Shams

MiddleName

-

Affiliation

Menoufia University, Faculty of Electronic Engineering, Physics and Mathematical Engineering Department, 32952 Menouf, Egypt.

Email

-

City

-

Orcid

-

Volume

65

Article Issue

13

Related Issue

37459

Issue Date

2022-12-01

Receive Date

2022-08-11

Publish Date

2022-12-01

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_257263.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=257263

Order

257,263

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Effect of increasing Fe-concentrations on ZnO thin film deposited by sol-gel spin coater.

Details

Type

Article

Created At

22 Jan 2023