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244775

High efficiency double-channel fluorescent Nickel (II) complex: syntheses, X-ray crystal structures, spectroscopy and surface checking Hirshfeld

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Inorganic chemistry

Abstract

Abstract

In that paper novel Ni(II) complex, derived from salemo-based ,Nickel(II) complex was synthesized, and characterized by elementary analysis, infrared spectroscopy, ultraviolet-visible absorption spectroscopy, single-crystal diffraction and Hirshfeld surface analyses. for detecting S2 and had a strong chemical fluorescence response. Via spectral analysis, S2 could be detected with high sensitivity and selectivity in the presence of different anions and used with the naked eye to detect S2. The solution colour was converted from colourless to bright yellow by the addition of S2 fibre. UV absorption, fluorescence and other methods of characterization were performed and the action mechanism was developed. I also visually inspected H2S gas, and the Ni(II) complex was able to detect S2 in gas molecules and show its possible use in biology and medicine.

DOI

10.21608/ejchem.2022.56091.3203

Keywords

fluorescence response, salamo-based, Characterization, Spectroscopic, X-ray single crystal

Authors

First Name

Haitham

Last Name

Dakheel

MiddleName

Kadhim

Affiliation

Department of chemistry , college of Education , university of Al-Qadisiyah, Dewanyia , 58, lraq

Email

hkazm0263@gmail.com

City

Qadisiyah

Orcid

-

First Name

Haider

Last Name

Hessoon

MiddleName

M.

Affiliation

3Department of Chemistry, College of Science, University of AL-Qadisiyah, Dewanyiah, Iraq

Email

hkad4982@gmail.com

City

-

Orcid

-

Volume

65

Article Issue

13

Related Issue

37459

Issue Date

2022-12-01

Receive Date

2020-12-31

Publish Date

2022-12-01

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_244775.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=244775

Order

244,775

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

High efficiency double-channel fluorescent Nickel (II) complex: syntheses, X-ray crystal structures, spectroscopy and surface checking Hirshfeld

Details

Type

Article

Created At

22 Jan 2023