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235882

Inhibition Efficiency of Erdosteine Drug for 304L Stainless Steel Corrosion and Its Solvation Thermodynamic Parameters

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Electrochemistry

Abstract

The effect of a new class of corrosion inhibitor, namely, Erdosteine drug on stainless steel 304L (304L SS) corrosion was investigated as potential corrosion inhibitor in 1 M HCl solution at 25°C. Measurements were conducted utilizing “weight loss (WL), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PP)" tests. From all tests, one can observe that with increasing doses of Erdosteine drug the inhibition efficacy was increased at 25°C. The adsorption of this drug on SS304L surface follows Langmuir adsorption isotherm. The inhibition efficacy increases with increasing the dose of the Erdosteine drug and decreases with rise in temperature of the medium. This drug may form a film which acts as a barrier, to minimize the contact area between 304L SS surface and HCl solution. Electrochemical results showed that this drug is efficient inhibitor for SS304L and the efficacy reached to 90 % at 300 ppm. The PP data showed that this drug acts as mixed mode mechanism. From the EIS examination, we notice the decrease in the values of double layer by increasing the dose of Erdosteine drug, on the other hand, the charge transfer resistance is increased. Thermodynamic parameters of activation and adsorption processes were calculated and discussed. The sign of the free energy of adsorption showed spontaneous process of adsorption and the stability of the adsorbed film. The surface morphology of the SS304L samples was estimated utilizing “Atomic Force Microscopy (AFM), X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy (FTIR)". Results gain for all tests used are in good agreement. To study the stability of Erdosteine and its interaction with solvent at different time intervals, different solvation thermodynamic parameters were determined from; density, refractive index and UV-spectra measurements.

DOI

10.21608/ejchem.2022.131748.5806

Keywords

304L SS, Corrosion inhibition, HCl, AFM, FTIR, Erdosteine drug, Solvation

Authors

First Name

farid

Last Name

El-Dossoki

MiddleName

-

Affiliation

Chemistry Department, Faculty of Science, Port Said University, Port Said, Egypt

Email

feldossoki64@gmail.com

City

-

Orcid

0000-0001-7795-4919

First Name

Abd elaziz

Last Name

Fouda

MiddleName

-

Affiliation

Chemistry,Faculty of Science, Mansoura University, Mansoura, Egypt

Email

asfouda@mans.edu.eg

City

-

Orcid

http://orcid.org/000

First Name

Ahmed

Last Name

El-Hossiany

MiddleName

-

Affiliation

Delta for Fertilizers and Chemical Industries, Talkha, Daqahlya 1179 Egypt

Email

dr.ahmedselm@gmail.com

City

-

Orcid

0000-0002-8118-2402

First Name

Eladl

Last Name

Hamed

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science, El-Mansoura University

Email

justic97@yahoo.com

City

-

Orcid

-

Volume

65

Article Issue

13

Related Issue

37459

Issue Date

2022-12-01

Receive Date

2022-04-05

Publish Date

2022-12-01

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_235882.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=235882

Order

235,882

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Inhibition Efficiency of Erdosteine Drug for 304L Stainless Steel Corrosion and Its Solvation Thermodynamic Parameters

Details

Type

Article

Created At

22 Jan 2023