235391

Application of Low-Cost Adsorption Technique on Organic Pollutant Dye Removal by Bio-Waste Adsorbents

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Environmental chemistry

Abstract

This study focused on studying the kinetics, thermodynamics, and the adsorption equilibrium of Acid fuchsin, C.I acid violet 19 (AV19) dye from aqueous media by using different adsorbent such as Caw Animal Bone (CAB) and Hen Eggshell (HES) as a new cheap, low-cost, widely available, eco-friendly, high-efficiency adsorbents. Scanning electron microscopy (SEM) and Fourier transform infrared spectrometer (FTIR) techniques were used to characterize the adsorbent before and after adsorption process. The influence of different conditions had been examined such as pH solution, initial dye concentrations, adsorbent dose, adsorbent sizes, contact time and different temperatures. The equilibrium data was analyzed by Langmuir and Freundlich's isotherm models and showed a good fit with the Langmuir model more than Freundlich's isotherm model (R2= 0.997), and a pseudo-second order kinetic is the best model suggested to explain the kinetics model with a good agreement with the intra-particle diffusion model. The parameters of thermodynamic including enthalpy ΔH°, entropy ΔS° and free energy ΔG° demonstrated that the adsorption process was feasible, spontaneous, and endothermic in nature of the adsorption of AV19 on CAB and exothermic nature of adsorption of AV19 on HES. The results clarified that a large percentage removal and the optimized conditions were (4±0.2 and 2±0.2) solution pH, 3.82mg/L initial dye concentration, adsorbent dose 0.75 gm/40 ml of particle size (2.36 and 0.355), for CAB and HES respectively and 60 min adsorption time 81.2% and 91.4% of dye was removed by CAB and HES respectively at experimental optimum conditions. The experimental results show that CAB and HES have a good potential as adsorbent to remove the colour from textile effluent and as an alternate low-cost adsorbent.

DOI

10.21608/ejchem.2022.132441.5847

Keywords

Cow Animal Bone, Hen Egg Shell, Low-Cost Adsorption, Acid violet 19, Adsorption isotherm, Kinetics

Authors

First Name

Heba

Last Name

El-Refay

MiddleName

Mohamed

Affiliation

Yousef Abbas Str., Nasr City, Cairo, Egypt

Email

hebaelrefay.5919@azhar.edu.eg

City

11754- Egypt

Orcid

-

First Name

Asmaa

Last Name

Raslan

MiddleName

M.

Affiliation

Ministry of Environment, Egptian Environmental Affair Agency, 30 Misr Helwan El-Zyrae Road, Maadi, Cairo, Egypt

Email

raslan01017@gmail.com

City

-

Orcid

-

First Name

A.M.

Last Name

Attia

MiddleName

E.

Affiliation

Department of Chemistry, Faculty of Science (Gils), Al-Azhar University (Girls), Yousef Abbas

Email

amanyatia8805@gmail.com

City

-

Orcid

-

Volume

65

Article Issue

13

Related Issue

37459

Issue Date

2022-12-01

Receive Date

2022-04-09

Publish Date

2022-12-01

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_235391.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=235391

Order

235,391

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Application of Low-Cost Adsorption Technique on Organic Pollutant Dye Removal by Bio-Waste Adsorbents

Details

Type

Article

Created At

22 Jan 2023