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234458

Solvation thermodynamics of Allyl and Butyl-Methyl Imidazolium Ionic Liquids in Aqueous and Alcoholic-Aqueous Solvents

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Physical chemistry

Abstract

Conductivity, density, refractive index and ultra-violet of 1-Allyl-3-methylimidazolium chloride (AMImCl)and 1-butyl-3-methylimidazolium hexaflourophosphate (BMImPF6) ionic liquids (ILs)At 298.15 K, Mixed solvents have been tested with different mole fractions of alcohols, containing aqueous and alcoholic-aqueous (methanol, ethanol, and glycerol). The conductivity and surface tension and refractive index and ultra-violet measurements were used to assess the critical micelle concentration (CMC) of (AMImCl) and (BMImPF6). The CMC was found to increase as the alcohol mole fraction increased in all solvents used. The results indicate that the CMC of (AMImCl) and (BMImPF6) methanol, ethanol, and glycerol, in that order. Micellization was discovered to be a naturally occurring process. The molal volume of the two surfactants was calculated and discussed based on the density information. The polarizability and molal refraction of AMImCl and BMImPF6 were also measured and discussed using the refractive index results. For all calculations, a computer programmer was used.

DOI

10.21608/ejchem.2022.117132.5286

Keywords

CMC, AMImCl, BMImPF6, Molal volume, refractive index

Authors

First Name

farid

Last Name

El-Dossoki

MiddleName

-

Affiliation

Chemistry Department, Faculty of Science, Port Said University, Port Said, Egypt

Email

feldossoki64@gmail.com

City

-

Orcid

0000-0001-7795-4919

First Name

Esam

Last Name

Arafa

MiddleName

-

Affiliation

Chemistry department, Faculty of Science, Mansoura University, Egypt

Email

esam1947@yahoo.com

City

-

Orcid

-

First Name

Mohamed

Last Name

Ali

MiddleName

-

Affiliation

POTEX PHARMACompany for pharmaceutical drugs, Cairo, Egypt

Email

mhamed@gmail.com

City

-

Orcid

-

Volume

65

Article Issue

13

Related Issue

37459

Issue Date

2022-12-01

Receive Date

2022-01-18

Publish Date

2022-12-01

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_234458.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=234458

Order

234,458

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Solvation thermodynamics of Allyl and Butyl-Methyl Imidazolium Ionic Liquids in Aqueous and Alcoholic-Aqueous Solvents

Details

Type

Article

Created At

22 Jan 2023