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228805

Improvement of the Adsorption Efficiency of Rice Husk Ash for Crystal Violet Dye Removal from Aqueous Medium

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Physical chemistry

Abstract

Rice husk ash (RHA) product was chemically modified and utilized for the adsorption of toxic dye from water. The textile dye (crystal violet) was removed from aqueous media using Rice Husk Ash (RHA) and Chemically Modified Rice Husk Ash (CMRHA) as adsorbents. The effects of stirring time, dye concentration, adsorbent dose, pH and temperature on the adsorption capacity were studied. The chemical modification of RHA enhanced the absorption efficiency from 88.9% to 99.1% at pH 6 and room temperature by using 2g/L of adsorbents. Thermodynamics study indicated that the process is exothermic and spontaneous. The kinetics study indicated that the adsorption process for the two adsorbents best fitted to the pseudo-second order kinetics model. The equilibrium data were tested with Langmuir, Freundlich, and Temkin equations. It was investigated that data best fitted to the Langmuir and Temkin models, which indicated for chemisorptions process and heterogeneous surface of the adsorbents.

DOI

10.21608/ejchem.2022.122775.5496

Keywords

Keywords: Rice husk, Chemical modification, Adsorption, Crystal violet dye, isotherms

Authors

First Name

Abbas

Last Name

Khan

MiddleName

-

Affiliation

Department of Chemistry, Abdul Wali Khan University Mardan, 23200 Pakistan

Email

abbas053@gmail.com

City

-

Orcid

-

First Name

Abdul

Last Name

Malik

MiddleName

-

Affiliation

Department of Chemistry, Abdul Wali Khan University Mardan, 23200 Pakistan.

Email

abdul_malik811@yahoo.com

City

-

Orcid

-

First Name

Muhammad

Last Name

Humayun

MiddleName

-

Affiliation

Engineering Research Center for Functional Ceramics of the Ministry of Education, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan, 430074, PR China.

Email

humayun096@yahoo.com

City

-

Orcid

-

First Name

Nasrullah

Last Name

Shah

MiddleName

-

Affiliation

Department of Chemistry, Abdul Wali Khan University Mardan, 23200 Pakistan

Email

nasrchem@gmail.com

City

-

Orcid

-

First Name

Muhammad

Last Name

Ismail

MiddleName

-

Affiliation

Department of Chemistry, Woman University Swabi, Pakistan.

Email

ismail_wazirs@yahoo.com

City

-

Orcid

-

First Name

Mohamed

Last Name

Yahia

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science, Helwan University, Ain-Helwan, 11795 Cairo, Egypt.

Email

yahia_sci@yahoo.com

City

Cairo

Orcid

0000-0001-8915-2921

First Name

Rasha M.K.

Last Name

Mohamed

MiddleName

-

Affiliation

- Chemistry Department, Faculty of Science, Assiut University, P.O. Box: 71515, Assiut, EgyptŲ² - Chemistry Department, College of Science, Jouf University, P.O. Box: 2014, Sakaka, Saudi Arabia

Email

rasha_kamal99@yahoo.com

City

-

Orcid

-

Volume

65

Article Issue

13

Related Issue

37459

Issue Date

2022-12-01

Receive Date

2022-02-19

Publish Date

2022-12-01

Page Start

427

Page End

435

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_228805.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=228805

Order

228,805

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Improvement of the Adsorption Efficiency of Rice Husk Ash for Crystal Violet Dye Removal from Aqueous Medium

Details

Type

Article

Created At

22 Jan 2023