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222641

Conversion of Cellulose From Palm Oil Middle Waste (Elaeis Guineensis) Into Bio-Oil Products As Alternative Fuel

Article

Last updated: 01 Jan 2025

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Subjects

-

Tags

Environmental chemistry

Abstract

Oil palm midrib are very abundant waste, especially in the North Sumatra. Lignocellulose contained in oil palm midrib can be used as a source of alternative energy raw materials. The purpose of this research is to produce bio-oil that can reduce the use of fossil fuels. Natural zeolite (ZAS) as a catalyst was activated by mineral acid and calcination with nitrogen gas. Impregnation of Ni and Fe into ZAS followed by calcination and oxidation process to obtained Ni-Fe/ZAS catalyst. The conversion of oil palm midrib powder into cellulose was carried out by delignification process with NaOH and bleaching. Then, the conversion of bio-oil is carried out by pyrolysis using the HDO process. Based on the results of the catalyst characterization and activity test showed that the Ni-Fe/ZAS catalyst had good characteristics and activity. Bio-oil from fiber is dominated by lignin derivatives, meanwhile cellulose bio-oil is dominated by furan derivatives. Hydrodeoxygenation using a Ni-Fe/ZAS catalyst on fiber produced slightly different compounds from bio-oil in HDO without a catalyst, especially in the reduction percentage of phenol area from 52.91% to 39.58%. Meanwhile, in HDO bio-oil from cellulose, there was an increase in the percent area of ​​phenol from 27.45% to 35.59%.

DOI

10.21608/ejchem.2022.96526.4517

Keywords

Oil palm midrib, natural zeolite, Catalyst, bio-oil, Pyrolysis, hydrogenation

Authors

First Name

Adistya

Last Name

Husna

MiddleName

Fadhilah

Affiliation

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl. Willem Iskandar Pasar V Medan Estate, Medan 20221, Indonesia

Email

adistyafadhillahh@gmail.com

City

-

Orcid

-

First Name

Fitria

Last Name

Febrianti

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl. Willem Iskandar Pasar V Medan Estate, Medan 20221, Indonesia

Email

fitrrrria@gmail.com

City

-

Orcid

-

First Name

Habibie

Last Name

Syah

MiddleName

Helminan

Affiliation

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl. Willem Iskandar Pasar V Medan Estate, Medan 20221, Indonesia

Email

habibihabibi2550@gmail.com

City

-

Orcid

-

First Name

Rabiatul

Last Name

Pangaribuan

MiddleName

Adawiyah

Affiliation

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl. Willem Iskandar Pasar V Medan Estate, Medan 20221, Indonesia

Email

pangaribuanahda@gmail.com

City

-

Orcid

-

First Name

Tia

Last Name

Surbakti

MiddleName

Aulia

Affiliation

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl. Willem Iskandar Pasar V Medan Estate, Medan 20221, Indonesia

Email

tiaauliasrb09@gmail.com

City

-

Orcid

-

First Name

Junifa

Last Name

Sihombing

MiddleName

Layla

Affiliation

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl.Willem Iskandar Pasar V Medan Estate, Medan 20221, Indonesia

Email

junifalaylasihombing@unimed.ac.id

City

-

Orcid

0000-0003-4359-3443

First Name

Ahmad

Last Name

Pulungan

MiddleName

Nasir

Affiliation

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Negeri Medan, Jl. Willem Iskandar Pasar V Medan Estate, Medan 20221, Indonesia

Email

nasirpl@unimed.ac.id

City

-

Orcid

0000-0001-9024-6546

Volume

65

Article Issue

11

Related Issue

35761

Issue Date

2022-11-01

Receive Date

2021-09-17

Publish Date

2022-11-01

Page Start

61

Page End

67

Print ISSN

0449-2285

Online ISSN

2357-0245

Article File

EJCHEM_Volume 65_Issue 11_Pages 61-67.pdf

PDF . 716.5kB

Link

https://ejchem.journals.ekb.eg/article_222641.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=222641

Order

8

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Conversion of Cellulose From Palm Oil Middle Waste (Elaeis Guineensis) Into Bio-Oil Products As Alternative Fuel

Details

Type

Article

Created At

22 Jan 2023