213849

Inhibition by using (Ethyl-2-aminothiazole-4-carboxylate) for copper corrosion in an acidic media

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Physical chemistry

Abstract

The influence of Ethyl-2-aminothiazole-4-carboxylate as a copper corrosion inhibitor in 1M HCl acid was investigated using both weight loss and polarization techniques. At 40 oC by raising the inhibitor concentration reduces corrosion current density and rate while improving inhibition efficiency and surface coverage, on the other hand the efficiency decreases as temperature rises at 50 and 60 oC. By Increasing inhibitor concentrations led to higher activation, enthalpy, and free adsorption energy, as well as lowering entropy energy, demonstrating that the inhibitor have sufficient energy to initiate the adsorption process, through creation of a layer of film on the surface of the metal due to the presence of molecules of both amines and thiazole, as well as the presence of nitrogen, oxygen and sulfur atoms, which have an effective effect on inhibition and corrosion prevention indicating that it is an excellent form of inhibitor.

DOI

10.21608/ejchem.2022.110271.5018

Keywords

Polarization, weight loss, Enthalpy, Entropy, Corrosion, inhibition, Activation energy

Authors

First Name

Raheem

Last Name

Al-Uqaily

MiddleName

Aziz

Affiliation

wasit university

Email

raheem222888@yahoo.com

City

wasit

Orcid

0000-0001-9537-378X

First Name

Ruaa

Last Name

Muslim

MiddleName

Issa

Affiliation

Geology department, college of science, wasit university

Email

ralqurashy@uowasit.edu.iq

City

wasit

Orcid

-

First Name

SUBHI

Last Name

AL-BAYATY

MiddleName

Abdulsattar

Affiliation

Department of Chemistry, College of Science, Wasit University, Wasit , Iraq

Email

chemsubhi@gmail.com

City

wasit-Iraq

Orcid

-

Volume

65

Article Issue

10

Related Issue

34864

Issue Date

2022-10-01

Receive Date

2021-12-08

Publish Date

2022-10-01

Page Start

403

Page End

409

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_213849.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=213849

Order

36

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Inhibition by using (Ethyl-2-aminothiazole-4-carboxylate) for copper corrosion in an acidic media

Details

Type

Article

Created At

22 Jan 2023