212812

Agricultural By-Products as Green Chemistry in Elimination of Reactive Red 43 From Aqueous Media- Adsorption Properties, Kinetics and Thermodynamics Study

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Physical chemistry

Abstract

The aim of this study is to find an effective green waste (GW) natural material as an adsorbent for the removal of C.I. Reactive Red 43 (RR43) from an aqueous solution using batch experiments. Agricultural-by-products such as Peanut Shell (PS) and Corn Cobs (CC) have been used as (GW). Scanning electron microscopy (SEM) coupled with Energy Dispersive X-ray (EDX) and Fourier transform infrared spectrometer (FTIR) techniques were used to characterize the adsorbent before and after adsorption process. The influence of operating factors such as adsorbent dose, initial concentration of dye, contact time, pH solution and temperature were studied. The equilibrium data was analyzed by Langmuir and Freundlich isotherm models and showed a good fit with the Freundlich isotherm (R2=0.999). Batch kinetic data were analyzed using pseudo-first order and pseudo-second order kinetic models, the adsorption kinetics data were fitted to pseudo-second order kinetic model with a good agreement with the intra-particle diffusion model. The parameters of thermodynamic including enthalpy ΔH°, entropy ΔS° and free energy ΔG° demonstrated that the adsorption process was feasible, spontaneous, and exothermic in nature. The results clarified that a large percentage removal, and the optimized conditions were (7.6±0.2 and 4.3±0.2) solution pH for PS and CC respectively, 20mg/L initial dye concentration, adsorbent dose 0.1 gm/20 ml, and 90 min adsorption time. 80.46% and 86.76% of dyes were removed by PS and CC respectively at experimental optimum conditions. These agricultural by-products are renewable, biodegrade able, inexpensive, and easily accessible with little or no cost. Their application as adsorbents is in line with the current trend of green chemistry and green environmental policies.

DOI

10.21608/ejchem.2022.102614.4757

Keywords

Reactive Red 43 (RR43), Low-Cost Adsorbents, Adsorption isotherm, kinetic, Thermodynamic

Authors

First Name

Heba M.

Last Name

El-Refay

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science (Gils), Al-Azhar University (Girls),Yousef Abbas Str, P.O. Box:11754, Nasr City, Cairo, Egypt

Email

hebaelrefay.5919@azhar.edu.eg

City

11754- Egypt

Orcid

-

First Name

Asrar

Last Name

Goma

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science (Gils), Al-Azhar University (Girls),Yousef Abbas Str, P.O. Box:11754, Nasr City, Cairo, Egypt

Email

-

City

-

Orcid

-

First Name

Nagwa

Last Name

Badawy

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science (Gils), Al-Azhar University (Girls),Yousef Abbas Str, P.O. Box:11754, Nasr City, Cairo, Egypt

Email

nagwabadawy@yahoo.com

City

-

Orcid

-

First Name

Fatema Al Zahra

Last Name

Ghanem

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science (Gils), Al-Azhar University (Girls),Yousef Abbas Str, P.O. Box:11754, Nasr City, Cairo, Egypt

Email

-

City

-

Orcid

-

Volume

65

Article Issue

8

Related Issue

31862

Issue Date

2022-08-01

Receive Date

2021-10-25

Publish Date

2022-08-01

Page Start

97

Page End

108

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_212812.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=212812

Order

11

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Agricultural By-Products as Green Chemistry in Elimination of Reactive Red 43 From Aqueous Media- Adsorption Properties, Kinetics and Thermodynamics Study

Details

Type

Article

Created At

22 Jan 2023