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207996

Synthesis and Characterization of PVVH/ CuO Nanocomposite for Industrial Application

Article

Last updated: 01 Jan 2025

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Tags

Material science

Abstract

Polymer nanocomposite of poly(vinyl chloride-co-vinyl acetateco-2-hydroxypropyl acrylate) copolymer (PVVH) doped with different concentrations of Copper oxide nanoparticles (CuO NPs) is prepared using the casting technique method. The prepared nanocomposite samples are characterized using X-Ray Diffracted (XRD), Transmission Electron Microscope (TEM), Attenuated Total Reflection- Fourier Transform Infrared (ATR-FTIR), and optical properties are studied using the Ultraviolet-Visible technique (UV-Vis). XRD and ATR-FTIR of the prepared sample confirmed the interaction and complexation between PVVH and CuO NPs. Optical properties such as bandgap energy and Urbach energy indicate that the addition of CuO NPs into PVVH polymer induced variations in the number of available final states as a function of composition ratio. Also, CuO NPs changed the electronic structure PVVH by doping via deformation potential, formation of localized band states, and Coulomb interaction.

DOI

10.21608/ejchem.2021.104413.4820

Keywords

PVVH CuO NPs XRDOptical properties

Authors

First Name

Fatma

Last Name

Attia

MiddleName

-

Affiliation

Spectroscopy Department, National Research Centre, 33 El Bohouth Street, Dokki, 12622, Giza, Egypt.

Email

fa6ma3adel206@gmail.com

City

-

Orcid

-

First Name

Amr M.

Last Name

Abdelghany

MiddleName

-

Affiliation

Spectroscopy Department, National Research Centre, 33 El Bohouth Street, Dokki, 12622, Giza, Egypt., Basic Science Department, Horus University, International Coastal Rd, New Damietta, KafrSaad, Damietta, Egypt

Email

-

City

-

Orcid

-

First Name

Medhat A.

Last Name

Ibrahim

MiddleName

-

Affiliation

Spectroscopy Department, National Research Centre, 33 El Bohouth Street, Dokki, 12622, Giza, Egypt., Nanotechnology Research Centre (NTRC), The British University in Egypt (BUE), Suez Desert Road, El-Sherouk City, Cairo, 11837, Egypt.

Email

-

City

-

Orcid

-

First Name

Nagwa A.

Last Name

Hakeem

MiddleName

-

Affiliation

Spectroscopy Department, National Research Centre, 33 El Bohouth Street, Dokki, 12622, Giza, Egypt.

Email

-

City

-

Orcid

-

First Name

Nadra

Last Name

Nada

MiddleName

-

Affiliation

Physics Department, Faculty of Women for Arts, Science and Education, Ain Shams University, 11757 Cairo, Egypt.

Email

-

City

-

Orcid

-

Volume

65

Article Issue

7

Related Issue

31861

Issue Date

2022-07-01

Receive Date

2021-11-04

Publish Date

2022-07-01

Page Start

371

Page End

377

Print ISSN

0449-2285

Online ISSN

2357-0245

Article File

EJCHEM_Volume 65_Issue 7_Pages 371-377.pdf

PDF . 617.8kB

Link

https://ejchem.journals.ekb.eg/article_207996.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=207996

Order

37

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Synthesis and Characterization of PVVH/ CuO Nanocomposite for Industrial Application

Details

Type

Article

Created At

22 Jan 2023