Beta
192938

Studying the effect of gold nanoparticles on mixture of surfactant of sodium dodecyl benzene sulfonate (SDBS) surfactant and folic acid

Article

Last updated: 22 Jan 2023

Subjects

-

Tags

Nano chemistry

Abstract

Gold nanoparticles were prepared from yeast dough via gold salt reduction and their effect on rheology of a mixture of folic acid and the surfactant of sodium dodecyl benzene sulfonate (SDBS) was studied. The results revealed that the highest viscosity (pa. s7.1232×102) was at a ratio of 2/8, a temperature of 10oC and a concentration of 0.00004M of nano-gold. So, micelles growth is occurred by increasing nano-gold concentration. In the same manner, measuring the conductivity of the prepared solution revealed that there is a reverse proportion between conductivity and viscosity. Also, thermodynamic functions were calculated such as standard free energy (ΔGº), standard enthalpy (ΔH) and standard entropy (ΔSº) for the formed micelles together with calculating the micellization activation energy. Gold nanoparticles were prepared from yeast dough (Saccharomyces cerevisiae), via gold salt reduction, and the prepared nanoparticles were diagnosed by several techniques (UV-Vis.,x-ray, TEM, SEM), through which the results showed that the prepared gold particles have a purple colour at length (552nm) it has a spherical shape and is within the nano size that was specified by the Shearer equation. The effect of these prepared nanoparticles on the rheology of the mixture of folic acid and the surfactant of Sodium Dodecyl Benzene sulfonate was studied using different temperatures, as this study showed that the highest viscosity Its value was (pa. s7.1232×10 2) at the ratio (2/8) and at a temperature of 10Co and when the concentration of nano-gold was 0.00004M. If these results indicate that the growth of micelles increases with the increase in the concentration of the prepared nano-gold. The conductivity measurement of the solutions prepared for the mixture was also studied, as it was found that the conductivity increases as the viscosity decreases in the presence of nano-gold particles, which leads to an increase in the growth of micelles. From calculating the thermodynamic functions, it was found that the standard free energy (ΔGº) is negative, the standard enthalpy (ΔH) is negative and the standard entropy (ΔSº) is negative for the formed micelles.

DOI

10.21608/ejchem.2021.93005.4396

Keywords

Surfactant, viscosity, Thermodynamic, Folic acid, Gold nano, micelles

Authors

First Name

Liqaa

Last Name

Alwan

MiddleName

Hussein

Affiliation

Department of Chemistry, College of Education, University of Samarra, Samarra, Iraq

Email

ameerakamalkhaleel@gmail.com

City

-

Orcid

-

First Name

LAYLA

Last Name

AL JEBUR

MiddleName

A.

Affiliation

Department of Chemistry, College of Science,Tikrit University,Tikrit, Iraq

Email

laylaa.aljebur@gmail.com

City

-

Orcid

-

Volume

65

Article Issue

3

Related Issue

29682

Issue Date

2022-03-01

Receive Date

2021-08-28

Publish Date

2022-03-01

Page Start

385

Page End

394

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_192938.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=192938

Order

36

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

-

Details

Type

Article

Created At

22 Jan 2023