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182444

Synthesis and Characterization of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes with 2-Carboxy benzaldehyde Aroylhydrazones

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Inorganic chemistry

Abstract

A new metal complexes have been synthesized by a reaction of metal compounds contained Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) with two kinds of ligands that are 2-carboxy benzaldehyde 4-methylbenzoylhydrazone(CBMH) and 2-carboxy benzaldehyde picolinoyl hydrazine (CBPH), the ligands (CBMH and CBPH) were prepared by condensation of 2-carboxy benzaldehyde with 4-methylbenzoyl hydrazide or picolinoyl hydrazide, respectively. In fact, complexes[M(L-H)2]. xH2O were characterized by elemental analysis, molar conductance, magnetic susceptibility, and spectral measurements (UV-Vis, IR,). The hydrazones CBMH and CBPH act as monobasic tridentate ligands, in all their complexes. The ligand CBMH coordinated to the metal ions through the azomethine nitrogen, the carboxyl group oxygen, and the amide carbonyl group oxygen atoms, while the ligand CBPH coordinated through the carboxyl group oxygen, the azomethine nitrogen, and the pyridine ring nitrogen atoms. Physico-chemical studies suggest octahedral geometry for all metal(II) complexes.

DOI

10.21608/ejchem.2021.80176.3968

Keywords

complexes, Hydrazones, transition metals, Octahedral complexes

Authors

First Name

Amenah A.

Last Name

Alfares

MiddleName

-

Affiliation

Department of chemistry, College of science, University of Mosul, Mosul, Iraq

Email

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City

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Orcid

-

First Name

Lana A.

Last Name

Alnuaimy

MiddleName

-

Affiliation

Department of chemistry, College of science, University of Mosul, Mosul, Iraq

Email

-

City

-

Orcid

-

First Name

Abdul Ghany M.

Last Name

Al-Daher

MiddleName

-

Affiliation

Al-Noor university college, Mosul, Iraq

Email

-

City

-

Orcid

-

Volume

65

Article Issue

1

Related Issue

28750

Issue Date

2022-01-01

Receive Date

2021-06-11

Publish Date

2022-01-01

Page Start

271

Page End

278

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_182444.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=182444

Order

30

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Synthesis and Characterization of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes with 2-Carboxy benzaldehyde Aroylhydrazones

Details

Type

Article

Created At

22 Jan 2023