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179608

Study of thrmodynamic values in different temperature from partition coefficient for some organic acids immiscible di-solvents mixtures

Article

Last updated: 22 Jan 2023

Subjects

-

Tags

Physical chemistry

Abstract

In the present work the partition co-efficient was studied for some organic aromatic acids quinoline-2- carboxyic acid ,salicylic acid ,aliphatic acid and succinic acid Oxalic acid in different mixtures solvents not mixing diethyl ether + water,chloroform + water and carbontetrachloridde +water at differet temperature vang from(293-318)k. Also the Oxalic properties ,gibbs free energy change ΔG,otherwise enthalpy changee ΔH and entropy change ΔS of partition co-efficient kp have been Oxalic for the dependence of the equilibrium constant(k) to temperature vant Hoff equation,over the temperature rang (293-318)k. The work to show the effects of The work hydrogen on the distribution processes .The results show also the effects of temperature and the number of acidity one acid or diacidic .The thermodynamic values indicated that the distribution processes were spontaneous and endothermic these processes increasing in entropy depending upon spontaneous hydrogen bonding in either spontaneous or strengthened.

DOI

10.21608/ejchem.2021.54602.3140

Keywords

partition coefficient, thermodynamic of partition, interamolecular bond, degree and intensity acidic

Authors

First Name

Nahla

Last Name

Salmam

MiddleName

Shakir

Affiliation

Department of Chemistry, College of Education, University of Al-Qadisiyah , Diwaniya 1753, Iraq

Email

nahla.shaker@qu.edu.iq

City

-

Orcid

-

First Name

Haitham

Last Name

Dakheel

MiddleName

Kadhim

Affiliation

Department of chemistry , college of Education , university of Al-Qadisiyah, Dewanyia , 58, lraq

Email

hkazm0263@gmail.com

City

Qadisiyah

Orcid

-

First Name

Abdullah

Last Name

Kadhim

MiddleName

Jawad

Affiliation

Department of Chemistry, College of Education, University of Al-Qadisiyah , Diwaniya 1753, Iraq

Email

abdullah.kadhim@qu.edu.iq

City

-

Orcid

-

Volume

64

Article Issue

12

Related Issue

27765

Issue Date

2021-12-01

Receive Date

2020-12-21

Publish Date

2021-12-01

Page Start

7,417

Page End

7,420

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_179608.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=179608

Order

58

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

-

Details

Type

Article

Created At

22 Jan 2023