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165697

A Pd-Np/Ac‐Catalyzed Transfer-Hydrogenation of Mesityl Oxide to Methyl Isobutyl Ketone using Sodium Formate as Hydrogen Donor

Article

Last updated: 01 Jan 2025

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Subjects

-

Tags

Organic chemistry

Abstract

Methyl isobutyl ketone (MIBK) is an α,β-unsaturated carbonyl compound, which is often used as solvent and extractor for antibiotics in the pharmaceutical industry. One alternative to the synthesis of MIBK from mesityl oxide (MO) is through catalytic transfer hydrogenation (CTH) using various organic compounds as hydrogen donors in the presence of a catalyst. The purpose of this study was to synthesize MIBK from MO through the CTH reaction using sodium formate as the hydrogen donor and Pd nanoparticles deposited on the activated charcoal (Pd-NP/AC) as the catalyst. Based on the Gas Chromatography-Mass Spectrometry (GC-MS) analysis, the conversion value of MO was obtained in 97.3% and the yield of the MIBK formation was 10.5%. Meanwhile, the highest selectivity was obtained in 17% at 40° C. The results show that sodium formate can effectively be used to reduce MO into MIBK in the presence of Pd-NP/AC catalyst at 70° C for 5 hours.

DOI

10.21608/ejchem.2021.65929.3416

Keywords

Transfer hydrogenation, hydrogen donor, methyl isobutyl ketone, mesityl oxide, Pd-NP/AC, sodium formate

Authors

First Name

Dadan

Last Name

Sumiarsa

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Mathematics and Natural Science, Universitas Padjadjaran, Indonesia

Email

dadan.sumiarsa@unpad.ac.id

City

-

Orcid

-

First Name

Rani

Last Name

Maharani

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Padjadjaran

Email

r.maharani@unpad.ac.id

City

Bandung

Orcid

-

First Name

Achmad

Last Name

Zainuddin

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Padjadjaran

Email

achmadzainuddin@hotmail.com

City

Bandung Area, West Java, Indonesia

Orcid

-

First Name

Ace

Last Name

Hidayat

MiddleName

Tatang

Affiliation

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Padjadjaran

Email

ace.hidayat@unpad.ac.id

City

Jatinangor

Orcid

-

First Name

Otong

Last Name

Nurhilal

MiddleName

-

Affiliation

Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Padjadjaran

Email

otong.nurhilal@phys.unpad.ac.id

City

-

Orcid

-

Volume

64

Article Issue

9

Related Issue

27062

Issue Date

2021-09-01

Receive Date

2021-03-02

Publish Date

2021-09-01

Page Start

4,843

Page End

4,847

Print ISSN

0449-2285

Online ISSN

2357-0245

Article File

EJCHEM_Volume 64_Issue 9_Pages 4843-4847.pdf

PDF . 260.6kB

Link

https://ejchem.journals.ekb.eg/article_165697.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=165697

Order

14

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

A Pd-Np/Ac‐Catalyzed Transfer-Hydrogenation of Mesityl Oxide to Methyl Isobutyl Ketone using Sodium Formate as Hydrogen Donor

Details

Type

Article

Created At

22 Jan 2023