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148663

Green Recycling of Poly(ethylene terephthalate) Waste as Corrosion Inhibitor for Steel in Marine Environment

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Physical chemistry

Abstract

Green recycling of poly(ethylene terephthalate) plastic waste, in this respect, PET waste was subjected to de polymerization process with tri methylene glycol (1,3-propandiol) in the presence of manganese acetate (1.0 % w/w to the total Wight of the reactants) as trans esterification catalyst, the product is Bis-(3-hydroxy-propyl)-terephthalate, BHPT, as a non-ionic surfactant was separated and characterized by FT-IR and 1HNMR and evaluated as corrosion inhibitor for carbon steel alloy in artificial marine environment using chemical and electrochemical techniques. Effect of inhibitor concentrations and reaction temperature were studied. The chemical techniques used in this work are gravimetric, thermometric and atomic absorption spectroscopy(AAS), whereas the electrochemical techniques are open circuit potential, potentiodynamic polarization. The corrosion inhibition efficiency increases with increasing inhibitor concentrations and decreased by rising temperature. The maximum corrosion inhibition efficiency 96.5% was afforded using 300 ppm of the used inhibitor derived from plastic waste. Potentiodynamic polarization curves indicate that the used system act as mixed inhibitor. The data of AAS show that the iron(iii) ions Fe+3 concentrations were decreased by increasing inhibitor concentration. All the used techniques are in good agreement to each other (±2 %) and shows that the used drug acts as green corrosion inhibitors for steel in marine environment.

DOI

10.21608/ejchem.2021.54262.3145

Keywords

poly(ethylene terephthalate), green recycling of waste, steel corrosion, Potntiodynamic, gravimetric, thermometric, AAS

Authors

First Name

Reda

Last Name

Abdel Hameed

MiddleName

-

Affiliation

Chemistry Department, Faculty of Science, Al - Azhar University, Cairo, 11884, Egypt

Email

mredars2@yahoo.com

City

Cairo

Orcid

https://orcid.org/00

First Name

M.

Last Name

Al Elaimi

MiddleName

-

Affiliation

Basic Science Department, Preparatory Year, University of Ha’il, 1560, Hail, KSA

Email

m.alelaimi@gmail.com

City

Aman

Orcid

-

First Name

M.

Last Name

Qureshi

MiddleName

T.

Affiliation

Department of Physics, Hazara University, Mansehra Pakistan

Email

tauseefqureshi1981@gmail.com

City

Hazara

Orcid

-

First Name

M.F.

Last Name

Abd el-kader

MiddleName

H.

Affiliation

Biophysics Department, Faculty of science, Cairo University

Email

mfhamed@hotmail.com

City

Cairo

Orcid

-

First Name

A.

Last Name

Nassar

MiddleName

-

Affiliation

Faculty of Science, Department of Chemistry, Al-Azhar University,11884, Cairo, Egypt.

Email

nassar_tanta@yahoo.com

City

Cairo

Orcid

-

First Name

Meshari

Last Name

Aljohani

MiddleName

-

Affiliation

Department of chemistry, Faculty of Science, University of Tabuk,Tabuk 71491, KSA.

Email

mualjohani@ut.edu.sa

City

-

Orcid

0000-0002-4572-0314

First Name

Enas

Last Name

Arafa

MiddleName

Ismail

Affiliation

Egyptian petroleum research institiut

Email

enas.epri@yahoo.com

City

-

Orcid

-

Volume

64

Article Issue

5

Related Issue

23661

Issue Date

2021-05-01

Receive Date

2020-12-22

Publish Date

2021-05-01

Page Start

2,685

Page End

2,695

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_148663.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=148663

Order

45

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Green Recycling of Poly(ethylene terephthalate) Waste as Corrosion Inhibitor for Steel in Marine Environment

Details

Type

Article

Created At

22 Jan 2023