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146189

Cyclic Voltammetric studies of the interaction of cupric chloride with (Z)-4-oxo-4-((4-selenocyannatophenyl)amino) but-2-2nonic acid , (Chal) in KCl solutions using glassy carbon

Article

Last updated: 01 Jan 2025

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Subjects

-

Tags

Physical chemistry

Abstract

To predict and analyze the complexation behavior between the challcogen ligand (Chal) (Z)-4-oxo-4-((4-selenocyannatophenyl)amino) but-2-2nonic acid, and metal ion in aqueous solution cyclic voltammetric studies of copper chloride salt [CuCl2] in absence and presence of chalcogen ligand (Chal), (Z)-4-oxo-4-((4-selenocyannatophenyl)amino) but-2-2nonic acid were performed. From these studies, some values were evaluated (the values of solvation and kinetic parameters [Ep (peak potential), Ip (peak current), D (Diffusion coefficient), ΔEP (peak potential difference), E½ (half wave potential), ks (electron transfer rate constant), Г (surface coverage) and Qa (quantity of electricity)]. the effect of different scan rate and concentration of above the calculated quantities were evaluated and discussed.

DOI

10.21608/ejchem.2021.44261.2903

Keywords

Cyclic voltammetry, chalcogen ligand, (Z)-4-oxo-4-((4-selenocyannatophenyl) amino) but-2-2nonic acid Ip (peak current), E½ (half wave potential), ks (electron transfer rate constant)

Authors

First Name

Esam A.

Last Name

Gomaa

MiddleName

-

Affiliation

Chemistry Department, Faculty of Science, Mansoura University, 35516-Mansoura, Egypt

Email

esam.gomaa47@yahoo.com

City

Mansoura

Orcid

-

First Name

Farid I.

Last Name

El-Dossoki

MiddleName

-

Affiliation

Chemistry Department, Faculty of Science, Port Said University

Email

feldossoki@yahoo.com

City

El-Mahalla El-Kubra

Orcid

-

First Name

Rania R.

Last Name

Zaky

MiddleName

-

Affiliation

Chemistry Department, Faculty of Science, Mansoura University, 35516-Mansoura, Egypt

Email

rania.zaki@yahoo.com

City

-

Orcid

-

First Name

Saad

Last Name

Shaaban

MiddleName

-

Affiliation

Chemistry Department, Faculty of Science, Mansoura University, 35516-Mansoura, Egypt

Email

-

City

-

Orcid

-

First Name

Fatma A.

Last Name

Attia

MiddleName

-

Affiliation

Chemistry Department, Faculty of Science, Mansoura University, 35516-Mansoura, Egypt

Email

fa6ma3adel206@gmail.com

City

Mansoura

Orcid

-

Volume

64

Article Issue

5

Related Issue

23661

Issue Date

2021-05-01

Receive Date

2020-09-29

Publish Date

2021-05-01

Page Start

2,671

Page End

2,678

Print ISSN

0449-2285

Online ISSN

2357-0245

Article File

EJCHEM_Volume 64_Issue 5_Pages 2671-2678.pdf

PDF . 674.4kB

Link

https://ejchem.journals.ekb.eg/article_146189.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=146189

Order

43

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Cyclic Voltammetric studies of the interaction of cupric chloride with (Z)-4-oxo-4-((4-selenocyannatophenyl)amino) but-2-2nonic acid , (Chal) in KCl solutions using glassy carbon electrode.

Details

Type

Article

Created At

22 Jan 2023