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146190

Synthesis, Characterization, and X-ray Crystal Structure Analysis of Zinc(II) Complex Based on 2-benzimidazolethiole

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Inorganic chemistry

Abstract

A novel mononuclear complex of the type [Zn(S-2-BIT)3(O-SO3)(CH3OH)2] (where 2-BIT = 2-benzimidazolethiole) has been synthesized and characterized by elemental analysis, FT-IR spectroscopy, UV-Vis spectroscopy, and single crystal-crystal X-ray diffraction. The crystal structure of the complex show that crystallizes in the triclinic P(1 ) ̅space group, with a=9.2946(13) Å, b= 10.1997(13) Å, c= 17.345(3) Å, β=105.494(7)օ, V= 1516.3(4) Å3, R1= 0.0316, wR2= 0.0843. In this complex, the distorted tetrahedral arrangement around the Zinc(II) atom is formed by three sulfur atoms from the 2-MBI ligand and one oxygen atom from the sulfate ion. The crystal lattice structure of the complex also contains two uncoordinated methanol molecules that formed N-H...O and O-H...O intermolecular hydrogen bonds.

DOI

10.21608/ejchem.2021.55124.3155

Keywords

Zn(II) complex, S-donor ligand, X-ray crystallography, Distorted tetrahedral coordination

Authors

First Name

Karwan

Last Name

Ali

MiddleName

Omer

Affiliation

College of Science, University of Halabja, Halabja, Iraq

Email

karwan.ali@uoh.edu.iq

City

Halabja

Orcid

0000-0002-3831-5556

First Name

Hikmat

Last Name

Mohamad

MiddleName

Ali

Affiliation

Department of Chemistry , College of Education,University of Salahaddin-Erbil-Iraq

Email

hikmat.mohamad@su.edu.krd

City

Erbil

Orcid

0000-0002-3784-8318

First Name

Eric

Last Name

Hosten

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science, Nelson Mandela Metropolitan University, Port Elizabeth, South Africa

Email

eric.hosten@nmmu.ac.az

City

Port Elizabeth

Orcid

-

First Name

Thomas

Last Name

Gerber

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science, Nelson Mandela Metropolitan University, Port Elizabeth, South Africa

Email

thomas.gerber@nmmu.ac.az

City

Port Elizabeth

Orcid

-

Volume

64

Article Issue

5

Related Issue

23661

Issue Date

2021-05-01

Receive Date

2020-12-25

Publish Date

2021-05-01

Page Start

2,415

Page End

2,419

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_146190.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=146190

Order

18

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Synthesis, Characterization, and X-ray Crystal Structure Analysis of Zinc(II) Complex Based on 2-benzimidazolethiole

Details

Type

Article

Created At

22 Jan 2023