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130402

Kinetics and Mechanism of The Oxidation of 2-Methylindole by Alkaline Potassium Hexacyanoferrate(III)

Article

Last updated: 22 Jan 2023

OverviewSimilar Items

Subjects

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Tags

Physical chemistry

Abstract

The reaction of 2-methylindole with hexacyanoferrate(III) in alkaline media to produce the corresponding 2-methylindolin-3-one has been studied at constant temperature and ionic strength. The reaction followed first order kinetics with respect to [2-methylindole], [OH-] and [Fe(CN)63-]. The effects of added electrolytes, potassium hexacyanoferrate(II), relative permitivity and temperature have also been studied. On the basis of experimental observations, a probable reaction mechanism has been proposed.

DOI

10.21608/ejchem.2020.22459.2338

Keywords

2-methylindole, hexacyanoferrate(III), 2-methylindolin-3-one, kinetics and oxidation

Authors

First Name

Iqab

Last Name

Amer

MiddleName

Adel

Affiliation

Department of chemistry, Arab American University, Palestine

Email

iqab.dababat@aaup.edu

City

-

Orcid

-

Volume

64

Article Issue

3

Related Issue

21851

Issue Date

2021-03-01

Receive Date

2020-01-15

Publish Date

2021-03-01

Page Start

1,441

Page End

1,446

Print ISSN

0449-2285

Online ISSN

2357-0245

Article File

EJCHEM_Volume 64_Issue 3_Pages 1441-1446.pdf

PDF . 522.9kB

Link

https://ejchem.journals.ekb.eg/article_130402.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=130402

Order

33

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

-

Details

Type

Article

Created At

22 Jan 2023