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77289

Green process for adsorptive removal of ethion (O,O,O′,O′-tetraethyl S,S′-methylene bis(phosphorodithioate) from agricultural wastewater using modified surface of orange peel and apricot kernel

Article

Last updated: 22 Jan 2023

Subjects

-

Tags

Environmental chemistry

Abstract

Smart absorber with engineered surface, low cost price becomes utmost importance for application in water treatment. Pesticide represents the fatal problem in water contamination due to large quantity misused by the farmers. Ethion is a common contaminated insecticide found in wastewater, so it is really important for removal of ethion from contaminant water. Here, the adsorption characteristics of ethion and its degradation products were studied using modified and functionalized low cost adsorbent. The modified agricultural wastes [orange peels (OP) and the outer crust of apricot kernel (AK)] were characterized and analyzed. Physical and chemical depositions of ethion residues on the surface of absorbers (OP and AK) were utilized.Theoretical calculations/modelling on surfaces of OP and AK were studied using Langmuir and Freundlich isotherm model. The results show that the removal efficiency of ethion increased when the pH of adsorption system increased then decreased at pH greater than 7. The using of different adsorbent doses found that the 95.5 % ethion removal was achieved when 16.5 g/L of the outer crust of apricot kernel. The kinetic model shows that the ethion uptake with the orange peels and apricot kernel adsorbents is a pseudo-second order adsorption.

DOI

10.21608/ejchem.2020.24957.2482

Keywords

Ethion, Agricultural wastewater, Adsorbents, Kinetics, Isotherm

Authors

First Name

Reda

Last Name

Abdelhameed

MiddleName

-

Affiliation

Applied Organic Chemistry Department, National Research Centre, 33 EL Bohouth st., Dokki, Giza, Egypt.

Email

reda_nrc@yahoo.com

City

-

Orcid

-

First Name

Fathia

Last Name

Mahdy

MiddleName

-

Affiliation

Applied Organic Chemistry Department, National Research Centre, 33 EL Bohouth st., Dokki, Giza, Egypt.

Email

fathia_mahdy@yahoo.com

City

-

Orcid

-

First Name

Hassan

Last Name

Abdel-Gawad

MiddleName

-

Affiliation

Applied Organic Chem., Pesticides, NRC

Email

abdelgawadhassan@hotmail.com

City

Cairo

Orcid

0000-0002-6166-1342

First Name

Bahira

Last Name

Hegazi

MiddleName

-

Affiliation

Applied Organic Chemistry Department, National Research Centre, 33 EL Bohouth st., Dokki, Giza, Egypt.

Email

nrc_byh@yahoo.com

City

-

Orcid

-

Volume

63

Article Issue

10

Related Issue

17778

Issue Date

2020-10-01

Receive Date

2020-03-01

Publish Date

2020-10-01

Page Start

3,837

Page End

3,845

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_77289.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=77289

Order

24

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

-

Details

Type

Article

Created At

22 Jan 2023