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77280

Synthesis, Structural Properties of Hydrazine Carbodithioate Schiff Base and Their Metal Complexes and Evaluation of Their Biological Activity

Article

Last updated: 22 Jan 2023

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Subjects

-

Tags

Inorganic chemistry

Abstract

A new series of [Ni(II)L2](1), [Cu(II)L2](2) and [Co(II)L2](3)(L = benzyl-2-((1E,4E)-1,5-diphenylpenta-1,4-dien-3-ylidene) hydrazine carbodithioate) Schiff base metal complexes have been synthesized. The ligand and its metal complexes were characterized by elemental analysis, 1H NMR, UV-Vis, FT-IR and magnetic moment, molar conductance and thermal analysis. The electrochemical behaviors of these complexes were investigated by cyclic voltammetry in DMF. The spectroscopic analyses and magnetic moment value suggested four coordinated geometry for three metal complexes, tetrahedral structure of complex 1 and square planer structure of complex 2 and 3. The ligand and its metal complexes were evaluated for their antibacterial (Bacillus cereus, Bacillus subtilis, Escherichia coli) activities. The complex 1 and Complex 2 revealed moderate activity against both gram positive bacteria (B. cereus and B. subtilis) with the minimum inhibitory concentration (MIC) value of 256 microg/mL.

DOI

10.21608/ejchem.2020.20507.2230

Keywords

Hydrazine carbodithioate, Metal complexes, Spectroscopic studies, Thermal analysis, Antibacterial activities

Authors

First Name

Umme

Last Name

Sultana

MiddleName

Shaila

Affiliation

Chemistry Discipline, Khulna University, Khulna-9208, Bangladesh.

Email

shaila32sultana@gmail.com

City

Khulna

Orcid

-

First Name

Md. Ahsan

Last Name

Habib

MiddleName

-

Affiliation

Chemistry Discipline, Khulna University, Khulna-9208, Bangladesh.

Email

ahsanhru@ku.ac.bd

City

Khulna

Orcid

0000-0003-0311-425X

First Name

Md. Khairul

Last Name

Amin

MiddleName

-

Affiliation

Chemistry Discipline, Khulna University, Khulna-9208, Bangladesh.

Email

khairul.che@ku.ac.bd

City

Khulna

Orcid

-

First Name

Md.

Last Name

Mahiuddin

MiddleName

-

Affiliation

Chemistry Discipline, Khulna University, Khulna-9208, Bangladesh.

Email

mahiuddin.chem@ku.ac.bd

City

Khulna

Orcid

-

First Name

Md. Kudrat

Last Name

Zahan

MiddleName

-E-

Affiliation

Department of Chemistry, University of Rajshahi, Rajshahi-6205, Bangladesh.

Email

kudrat.chem@ru.ac.bd

City

Rajshahi

Orcid

0000-0001-8159-5293

First Name

A.B.M. Nazmul

Last Name

Islam

MiddleName

-

Affiliation

Chemistry Discipline, Khulna University, Khulna-9208, Bangladesh.

Email

nazmulchem@ku.ac.bd

City

Khulna

Orcid

0000-0002-0302-8215

Volume

63

Article Issue

10

Related Issue

17778

Issue Date

2020-10-01

Receive Date

2019-12-04

Publish Date

2020-10-01

Page Start

3,811

Page End

3,816

Print ISSN

0449-2285

Online ISSN

2357-0245

Article File

EJCHEM_Volume 63_Issue 10_Pages 3811-3816.pdf

PDF . 679.8kB

Link

https://ejchem.journals.ekb.eg/article_77280.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=77280

Order

20

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

-

Details

Type

Article

Created At

22 Jan 2023