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Corrosion Protection of Pure Titanium Implant in Artificial Saliva by Electro-Polymerization of Poly Eugenol

Article

Last updated: 22 Jan 2023

Subjects

-

Tags

Physical chemistry

Abstract

In this work, a titanium dental implant was modified by electro-polymerized of 4-allyl-2-methoxyphenol (Eugenol) using direct current lower than 3.5 volt. The modification of titanium dental implant was achieved to improve its corrosion resistant. Fourier transform infrared spectroscopy (FTIR) was employed to confirm the electro-polymerization of Eugenol to Poly Eugenol (PE) on pure titanium. Deposition of PE on titanium was confirmed by X-ray diffraction and was characterized by thermogravimetric analysis (TGA). The surface morphology of polymeric film were examined through scanning electron microscopy (SEM). Coated titanium by (PE) revealed a good corrosion protection efficiency even at temperature ranged (293- 323) K in artificial saliva. Where the corrosion current density decrease with increase the temperature. Activation energy and pre-exponential factor (kinetic parameters) were calculated and discussed. Also, thermodynamic values ΔG and ΔH were calculated.

DOI

10.21608/ejchem.2019.13617.1842

Keywords

PolyEugenol, Titanium, Electro-polymerizaion, dental implant

Authors

First Name

Haider

Last Name

AlMashhadani

MiddleName

Abdulkareem

Affiliation

Baghdad

Email

h_r200690@yahoo.com

City

Baghdad

Orcid

0000-0002-3940-3478

First Name

Khulood

Last Name

saleh

MiddleName

Abed

Affiliation

University of Baghdad College of Science Department of Chemistry

Email

khulood_abid@yahoo.com

City

-

Orcid

-

Volume

63

Article Issue

8

Related Issue

10594

Issue Date

2020-08-01

Receive Date

2019-06-12

Publish Date

2020-08-01

Page Start

2,803

Page End

2,811

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_71916.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=71916

Order

1

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

-

Details

Type

Article

Created At

22 Jan 2023