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88637

Chemical Functionalization of Cellulose-Poly(Glycidyl-Methacrylate) Graft Copolymer with Two Different Poly Amino Compounds

Article

Last updated: 01 Jan 2025

OverviewSimilar Items

Subjects

-

Tags

Polymer chemistry

Abstract

Two amino-functionalized cellulose-poly(glycidyl methacrylate) graft copolymers (AM-CPGMA), based on waste cotton fibers, were preparedby the aminization of selected cellulose-poly(glycidyl methacrylate) graft copolymer (CPGMA) produced at best polymerization conditions using diethylenetri-amine (DETA) and triethylenetetraamine (TETA). The different aminization parameters, namely the aminating agent/epoxy molar ratio, reaction time, liquor ratio, pHand temperature were investigated, and optimum reaction conditions were established. The two prepared amino-functionalized cellulose-poly(glycidyl methacrylate) graft copolymers (AM-CPGMA) were characterized by the FT-IR, thermal gravimetric analysis (TGA), surface area measurement using Brunauer–Emmett–Teller (BET) and Barrett-Joyner-Halenda (BJH) theories and scanning electron microscope (SEM). Thus obtained results were compared with the native cellulose and its graft copolymer.

DOI

10.21608/ejchem.2020.26122.2522

Keywords

Cotton fibers, glycidyl methacrylate, graft copolymerization, aminization

Authors

First Name

Ahmed Ibrahim

Last Name

Waly

MiddleName

-

Affiliation

Department of Pre-Treatment and Finishing of Cellulosic Fibres, National Research Centre, Cairo, Egypt.

Email

draiwaly@hotmail.com

City

Al-Giza

Orcid

-

First Name

Maaly Abdel Moneim

Last Name

Khedr

MiddleName

-

Affiliation

Chemical Engineering Department, National Research Centre, Cairo, Egypt.

Email

maalykhedr@yahoo.com

City

Al-Giza

Orcid

-

First Name

Hanaa Mohammed

Last Name

Ali

MiddleName

-

Affiliation

Chemical Engineering Department, National Research Centre, Cairo, Egypt.

Email

hanaamohamedaly2007@gmail.com

City

Al-Giza

Orcid

-

First Name

Islam

Last Name

Ahmed

MiddleName

-

Affiliation

Chemical Engineering Department, National Research Centre, Cairo, Egypt.

Email

islamesmael@yahoo.com

City

Al-Giza

Orcid

-

Volume

63

Article Issue

7

Related Issue

10593

Issue Date

2020-07-01

Receive Date

2020-03-18

Publish Date

2020-07-01

Page Start

2,673

Page End

2,682

Print ISSN

0449-2285

Online ISSN

2357-0245

Article File

EJCHEM_Volume 63_Issue 7_Pages 2673-2682.pdf

PDF . 1.4MB

Link

https://ejchem.journals.ekb.eg/article_88637.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=88637

Order

21

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Chemical Functionalization of Cellulose-Poly(Glycidyl-Methacrylate) Graft Copolymer with Two Different Poly Amino Compounds

Details

Type

Article

Created At

22 Jan 2023