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85807

Study of Co(II) Transfer through a Ceramic Supported Liquid Membrane Impregnated with Di-(2-ethylhexyl)phosphoric Acid (D2HEPA)

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Analytical chemistry

Abstract

The permeation of Co(II) and Pb((II) ions from an aqueous feed solution through a ceramic disc supported liquid membrane impregnated in D2HEPA as a carrier was studied. The effects of Co (II) and Pb (II) ions, HNO3 in feed phase and D2HEPA in kerosene, EDTA as stripping solution (0.1-2) mol/L in ceramic membrane concentrations have been studied. The concentration of cations increase in the feed phase due to an increase in flux from (15.8-21.2)×10−9 in the Co(II) and (7.22-14.83)x10-9 mol/m2.s in Pb(II) ions, concentration in the range (7.98–26.45)×10−4 mol/L for cobalt and(5.66-13.71)x10-4 mol/L for lead ions respectively, [H3O]+ increasing with [NO3]- from 2 mol/L results into an increase in cobalt ions flux.The optimum conditions for Co (II) ions transport at 2mol/L HNO3 in feed phase and 2mol/L D2HEPA in ceramic membrane. It has been showed that cobalt and lead ions in flux increases. Applying the studied conditions indicated more than 98.7% removal of Co(II) ions and 66.4% of Pb (II) respectively.

DOI

10.21608/ejchem.2020.19959.2203

Keywords

Ceramic disc, Supported liquid membrane, EDTA, D2HEPA, Permeation

Authors

First Name

Amany

Last Name

Kassem

MiddleName

-

Affiliation

Nuclear Fuel Chemistry,Atomic Energy Authority, Hot Labs. Center

Email

amany.kassem@ymail.com

City

-

Orcid

-

Volume

63

Article Issue

6

Related Issue

10592

Issue Date

2020-06-01

Receive Date

2019-11-22

Publish Date

2020-06-01

Page Start

2,345

Page End

2,353

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_85807.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=85807

Order

26

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Study of Co(II) Transfer through a Ceramic Supported Liquid Membrane Impregnated with Di-(2-ethylhexyl)phosphoric Acid (D2HEPA)

Details

Type

Article

Created At

22 Jan 2023