Beta
46864

Facile Hydrothermal Synthesis of Sm and Eu doped TiO2/Graphene Oxide Nanocomposites for Photocatalytic Applications

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Nano chemistry

Abstract

Lanthanide (Ln3+) doped TiO2 supported on Graphene oxide (GO) (Ln3+ =Eu3+ and Sm3+ ions) were prepared via a low cost and facile hydrothermal method. Structural, morphological and optical properties of the un-doped and Ln3+-doped nanocomposites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) equipped with energy dispersive X-ray (EDX), transmission electron microscopy (TEM), SBET surface area analysis, Fourier Transform Infrared Spectroscopy (FTIR), Raman spectroscopy (RS) and Diffuse Reflection Spectrometry (DRS). The photocatalytic activities of the catalysts were investigated by studying photo decolorization and photodegradation of Methylene Blue (MB).Among different composites, the results show that 0.015 mol% Eu3+-doped TiO2/GO nanocomposite possesses the highest photocatalytic activity. Chemical oxygen demand (COD) analyses indorsed the photodegradation results. This promising photocatalyst led to almost complete mineralization of MB dye after only 90 min upon expose to UV light. The results clearly demonstrate the beneficial role of both the GO as a supporting material and the lanthanide metal ions as dopants on the degradability of MB.

DOI

10.21608/ejchem.2019.15112.1914

Keywords

photocatalysis, Lanthanide doped Titania, graphene oxide, methylene blue (MB), UV light

Authors

First Name

mariam Sh.

Last Name

gohr

MiddleName

-

Affiliation

Nanotechnology and New Composite Materials Department Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Bourg El-Arab City 21934, Alexandria, Egypt

Email

mariam.gohr@gmail.com

City

Alexandria

Orcid

0000-0003-3719-0058

First Name

Hoda

Last Name

Hafez

MiddleName

S.

Affiliation

Environmental Studies and Research Institute (ESRI), University of Sadat City (USC), Menofia, Egypt

Email

hoda.hafez@esri.usc.edu.eg

City

-

Orcid

-

First Name

Mona M.

Last Name

Saif

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Education, Ain Shams University, Roxy, 11341, Cairo, Egypt

Email

mona_saif1@yahoo.com

City

Cairo

Orcid

-

First Name

Hesham M. A.

Last Name

Soliman

MiddleName

-

Affiliation

Nanotechnology and New Composite Materials Department Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Bourg El-Arab City, 21934, Alexandria, Egypt

Email

h.soliman@srtacity.sci.eg

City

Alexandria

Orcid

0000-0003-4000-1297

First Name

M. S. A.

Last Name

Abdel-Mottaleb

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science, Ain Shams University

Email

m.s.abdelmottaleb@sci.asu.edu.eg

City

Cairo

Orcid

0000-0002-4437-7040

Volume

63

Article Issue

4

Related Issue

10590

Issue Date

2020-04-01

Receive Date

2019-07-22

Publish Date

2020-04-01

Page Start

1,359

Page End

1,382

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_46864.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=46864

Order

15

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Facile Hydrothermal Synthesis of Sm and Eu doped TiO2/Graphene Oxide Nanocomposites for Photocatalytic Applications

Details

Type

Article

Created At

22 Jan 2023