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68300

Synthesis, characterization and application of reactive UV absorbers for enhancing UV protective properties of cotton fabric

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Organic chemistry
Textile chemistry

Abstract

Two colourless reactive UV absorbers 1 and 2 were synthesized by the condensation reaction of both 2,4,6-trichlorotriazine and sulfanilinic acid with 4-aminobenzophenone and ethyl 4-aminobenzoate, respectively. The structures of UV absorbers 1 and 2 were confirmed by IR, NMR (1H and 13C), and elemental analysis. The synthesized reactive UV absorbers were applied to cotton fabric using pad-dry method in comparison with both exhaustion and microwave methods. The results showed that excellent ultraviolet protection factor (UPF) values were achieved on sodium hydroxide-treated cotton fabric using pad-dry method. The optimal conditions using pad-dry method, such as drying temperature, drying time and UV absorber concentration were discussed. It was found that the highest values of UPF and whiteness using reactive UV absorbers 1 and 2 especially after washing can be obtained in the conditions of 80 ºC drying temperature, 3 hours drying time and 15 g/l UV absorber concentration. The new reactive UV absorber 1 achieved excellent UPF value (58.2) compared to UV absorber 2 which exhibited poor UPF value (10.5) at the same conditions.

DOI

10.21608/ejchem.2020.22140.2324

Keywords

Reactive UV absorbers, UPF, Whiteness, Pad-dry method, Sodium hydroxide-treated cotton fabric

Authors

First Name

Hekmat I.

Last Name

Ibrahim

MiddleName

-

Affiliation

Dyeing, Printing & Auxiliaries Department, Textile Research Division, National Research Centre, Giza, Egypt

Email

hekmatismail1991@yahoo.com

City

Giza

Orcid

0000-0002-4908-3228

First Name

Reham

Last Name

Farouk

MiddleName

-

Affiliation

Dyeing, Printing & Auxiliaries Department, Textile Research Division, National Research Centre, Giza, Egypt

Email

rfabdelhady@hotmail.com

City

-

Orcid

-

First Name

Elham A.

Last Name

El-karadly

MiddleName

-

Affiliation

Dyeing, Printing & Auxiliaries Department, Textile Research Division, National Research Centre, Giza, Egypt

Email

elham_elkaradly@yahoo.com

City

-

Orcid

-

First Name

Ahmed

Last Name

Elwahy

MiddleName

H. M.

Affiliation

Chemistry Department, Faculty of Science, Cairo University, Giza, Egypt

Email

aelwahy@hotmail.com

City

-

Orcid

-

First Name

Abdalla.

Last Name

A. Mousa

MiddleName

-

Affiliation

Dyeing, Printing & Auxiliaries Department, Textile Research Division, National Research Centre, Giza, Egypt

Email

mousanrc@gmail.com

City

-

Orcid

-

Volume

63

Article Issue

2

Related Issue

10586

Issue Date

2020-02-01

Receive Date

2020-01-08

Publish Date

2020-02-01

Page Start

525

Page End

536

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_68300.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=68300

Order

15

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Synthesis, characterization and application of reactive UV absorbers for enhancing UV protective properties of cotton fabric

Details

Type

Article

Created At

22 Jan 2023