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Preparation of Nylon-6 Textile Materials for Special Applications Part1: Polymerization of 2-Methacryloxy Ethyl Trimethyl Ammonium Chloride with Nylon-6 Nonwoven Fabric Using K2S2

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Organic chemistry

Abstract

In the present work, a novel method was designed to develop an efficient and generally applicable technique for the creation of quaternary ammonium groups in nylon-6 macromolecules via polymerization of 2-methacryloxy ethyltrimethyl ammonium chloride (VQAs) in the presence of nylon-6 nonwoven fabrics using potassium persulphate (K2S2O8) as initiator. In addition factors affecting the extent and rate of polymerization (Rp) were investigated and the apparent activation energy was calculated. The reaction mechanism was suggested. Characterization of the grafted with PVQAs Nylon-6 nonwoven fabrics was investigated by X-ray, SEM, and FT-IR.

DOI

10.21608/ejchem.2019.13236.1824

Keywords

Nonwoven nylon-6 fabric, grafting, VQAs, PVQAs

Authors

First Name

Rafaat

Last Name

Abbas

MiddleName

-

Affiliation

Protein and Man made fibers department, Textile research Division, National research centre

Email

raafat_abas@hotmail.com

City

-

Orcid

-

First Name

Naser

Last Name

Al-Balakocy

MiddleName

Gad

Affiliation

Proteinic & Man made fibers

Email

nasergad@yahoo.com

City

Cairo

Orcid

0000-0002-8597-3308

First Name

E. M

Last Name

Khalil

MiddleName

-

Affiliation

Chemistry Department, Faculty of Science, Helwan University, Cairo, Egypt

Email

-

City

-

Orcid

-

First Name

Samy

Last Name

Shalaby

MiddleName

Elsebaie

Affiliation

Proteninic & Manmade Fibers Department, Textile Research Division, National Research Centre, Dokki, Cairo, Egypt

Email

samyshalaby40@yahoo.com

City

-

Orcid

0000-0003-3148-2877

Volume

62

Article Issue

Special Issue (Part 2) Innovation in Chemistry

Related Issue

10565

Issue Date

2019-12-01

Receive Date

2019-05-26

Publish Date

2019-12-01

Page Start

491

Page End

503

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_35314.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=35314

Order

7

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Preparation of Nylon-6 Textile Materials for Special Applications Part1: Polymerization of 2-Methacryloxy Ethyl Trimethyl Ammonium Chloride with Nylon-6 Nonwoven Fabric Using K2S2O8 As Initiator

Details

Type

Article

Created At

22 Jan 2023