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37681

Synthesis, Spectroscopic, Antibacterial and Antioxidant Activities of Pd(Ii) Mixed-Ligand Complexes Containing Tridentate Schiff Bases

Article

Last updated: 22 Jan 2023

Subjects

-

Tags

Inorganic chemistry

Abstract

Pd(II) complexes of the form [PdLNH3] (where L = N-salicylidene-o-aminophenol (L1), N-(5-methoxysalicylidene-o-aminophenol) (L2) and N-(2-hydroxy-1-naphthalidene)-o-aminophenol) (L3) containing ammonia and ONO tridentate Schiff bases were synthesized. These complexes were characterized by elemental analysis, infrared, ultraviolet-visible, proton and carbon-13 spectroscopies. The NMR spectra showed that the Schiff bases coordinated to the palladium(II) ion through the two deprotonated phenolic oxygen and azomethine nitrogen atoms. The presence of ammonia molecules in these complexes were indicated by the IR and 1H NMR spectra. The spectral data suggested a square planar geometry for the complexes. The biological studies revealed that the complexes displayed better antibacterial and antioxidant activities than the parent Schiff bases.

DOI

10.21608/ejchem.2019.12319.1766

Keywords

Schiff base, complex, Palladium(II) ion, Antibacterial, antioxidant

Authors

First Name

Abidemi

Last Name

Demehin

MiddleName

Iyewumi

Affiliation

Department of Chemistry, Adeyemi College of Education Ondo, Nigeria.

Email

demehinai@gmail.com

City

-

Orcid

-

First Name

Mary

Last Name

Oladipo

MiddleName

Adelaide

Affiliation

Department of Pure and Applied Chemistry, Ladoke Akintola University, Ogbomo, Oyo state, Nigeria

Email

moolapipupo@lautech.edu.ng

City

Ogbomoso

Orcid

0000-0001-9179-3883

First Name

Banjo

Last Name

Semire

MiddleName

-

Affiliation

Department of Pure and Applied Chemistry, Ladoke Akintola University of Technology, Ogbomoso, Nigeria

Email

bsemire@lautech.edu.ng

City

-

Orcid

-

Volume

62

Article Issue

Special Issue (Part 2) Innovation in Chemistry

Related Issue

10565

Issue Date

2019-12-01

Receive Date

2019-04-26

Publish Date

2019-12-01

Page Start

413

Page End

426

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_37681.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=37681

Order

2

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

-

Details

Type

Article

Created At

22 Jan 2023