Beta
37215

Treatment of Industrial Electroplating Wastewater by Electrochemical Coagulation Using Carbon and Aluminum Electrodes

Article

Last updated: 22 Jan 2023

Subjects

-

Tags

Environmental chemistry

Abstract

Electroplating wastewater is considered one of the most hazardous liquid wastes due to the presence of high contraction of toxic metals. Consequently, treatment of such wastewater is essential to protect the environment and waterways. Heavy metal ions are frequently of high toxicity and require treatment to the allowable standards for wastewater discharge. Electrochemical methods are more suitable for heavy metals removal due to their ability to reduce metal concentration to less than the permissible limits as well as allowing recovery of valuable metals. The aim of the present study is treatment of real electroplating wastewater. For this purpose, synthetic as well as real electroplating wastewaters were examined using soluble aluminium electrodes and insoluble carbon electrode along with ferric chloride and / or alum as coagulants. Factors affecting this treatment process were studied extensively, namely: current intensity, material of the electrode, pH and time. The obtained results proved that the best removal was achieved at 30 minutes and a potential difference 15 volt for aluminum electrode and 10 volts for carbon electrode. The later was combined with ferric chloride as coagulant. When the synthetic solution was examined by using aluminum electrode, the removal rate reached 97.2%, 97% and 96% for Zn, Cu, and Ni, respectively. By using carbon electrode in combination with ferric chloride, the respective removal rate reached 97.5%, 97.2% and 97.1%. By using the real electroplating wastewater and aluminum electrode, the removal rate reached 80%, 76.6% and 93.4% for Zn, Cu, and Ni respectively and by using carbon electrode and ferric chloride the achieved removal rate was 81.6%, 77.3% and 94.4% successively. It was concluded that the use of carbon electrode with FeCl3 is more suitable than aluminum electrode due to the dissolution of aluminum ions from electrode into the solution.

DOI

10.21608/ejchem.2019.11667.1742

Keywords

Electro-chemical treatment, electroplating wastewater, Electrocoagulation, Heavy Metals Removal, potential difference, Wastewater

Authors

First Name

Hussein

Last Name

Abdel-Shafy

MiddleName

Ibrahim

Affiliation

Water Research & Pollution Control Department, National Research Center, Dokki, Cairo, Egypt

Email

hshafywater@yahoo.com

City

Cairo

Orcid

0000-0002-3381-2617

First Name

Mahmoud A.I.

Last Name

Hewehy

MiddleName

A.I.

Affiliation

Institute of Environmental Studies and Research, Ain Shames University, Abasiyia, Cairo, Egypt.

Email

hewehy@yahoo.com

City

Cairo

Orcid

-

First Name

Taha

Last Name

Razek

MiddleName

M. A.

Affiliation

Institute of Environmental Studies and Research, Ain Shames University, Abasiyia, Cairo, Egypt

Email

taha_razek@gmail.com

City

Cairo

Orcid

-

First Name

Maamoun

Last Name

Hamid

MiddleName

M .A.

Affiliation

Central Metallurgical Research and Development Institute (CMRDI), Helwan, Cairo, Egypt

Email

maamoun_hamid@yahoo.com

City

Cairo

Orcid

-

First Name

Rehan

Last Name

Morsy

MiddleName

M.M.

Affiliation

Institute of Environmental Studies and Research, Ain Shames University, Abasiyia, Cairo, Egypt.

Email

rehan_mohamed2002@hotmail.com

City

Cairo

Orcid

-

Volume

62

Article Issue

Special Issue (Part 1) Innovation in Chemistry

Related Issue

9520

Issue Date

2019-12-01

Receive Date

2019-04-07

Publish Date

2019-12-01

Page Start

383

Page End

392

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_37215.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=37215

Order

29

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

-

Details

Type

Article

Created At

22 Jan 2023