Beta
32497

Flow ability Enhancement of Waxy Crude Oil Using New Spirocompound based on Aromatic Amine System

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Organic chemistry

Abstract

This work was focused on an investigating of flow ability of waxy crude oil by nontraditional polymer compound. For this propose, a spirocompound consisted of benzaldehyede and triethanolamine 6,6'-(((phenylmethylene) bis (oxy)) bis (ethane-2,1-diyl)) bis (2-phenyl-1,3,6-dioxazocane) [SB] was synthesized using zeolite as a catalyst. The chemical structure of the [SB] was investigated by FT-IR, TGA,GPC, H1NMR and Mass spectroscopy. The rheological behavior and pour point depression of waxy crude oil were also studied different dosages and temperatures. The results showed a significant reduction in the viscosity at different temperatures and dosages. Moreover, it was noticed a decrease in the apparent viscosity and the Bingham yield value for [SB] 437.7, 367.1, and 307.1 cp and 0.48, 0.39 and 0.31 Pa at 15 ºC, 20 ºC and 30 ºC and concentration 1000 ppm respectively. While the blank experiment displayed 743.1, 694.2 and 607.2 cp and 0.74, 0.69 and 0.60 Pa at the same temperatures. This study included blends between [SB] and the acrylate based polymers abbreviated as (B1, B2, B3 and B4). Furthermore, the rheological behavior and the pour point for these blends exhibited that the blend [B4] shew more reduction in the apparent viscosity than [SB] being alone. The apparent viscosity and yield value for [B4] were; 267.8, 249.2 and 212.7 cp and 0.22, 0.11 and 0.09 Pa at 15ºC, 20ºC and 30ºC and concentration 1000 ppm respectively. The pour point depression (Δpp) of [SB] was 9ºC while the blank pour point was 27 º C and the B4 was achieved the maximum depression in the pour point (Δpp= 18 º C) at a concentration of 1000 ppm. This result means that the addition of [SB] to [B4] showed the most positive synergistic effect.

DOI

10.21608/ejchem.2019.11135.1714

Keywords

Spiro compound, Wax Crude Oil, Pour Point, rheology, Physical Blends

Authors

First Name

Ahmed

Last Name

Al-Sabagh

MiddleName

-

Affiliation

Egyptian petroleum research institute, Nasr city, Cairo, Egypt

Email

alsabaghh@gmail.com

City

-

Orcid

-

First Name

Tahany

Last Name

Mahmoud

MiddleName

-

Affiliation

Petroleum application department , Egyptian Petroleum Research Institute

Email

tahany.mahmoud.a@gmail.com

City

-

Orcid

-

First Name

Maher

Last Name

Helal

MiddleName

Helmy

Affiliation

Faculty of Science , Helwan University

Email

toto.mood@yahoo.com

City

-

Orcid

-

First Name

Abd Ellatif

Last Name

Abd Elrahman

MiddleName

-

Affiliation

Egyptian Petroleum Research Institute

Email

sabaghh@epri.sci.eg

City

-

Orcid

-

First Name

Amira

Last Name

E. M. Abdallah

MiddleName

-

Affiliation

Faculty of science , Helwan university

Email

amira.sayed34@hotmail.com

City

-

Orcid

-

First Name

Mona

Last Name

El-Rayes

MiddleName

-

Affiliation

Egyptian Petroleum Research Institute

Email

mona.rayes@yahoo.com

City

-

Orcid

-

Volume

62

Article Issue

12

Related Issue

9517

Issue Date

2019-12-01

Receive Date

2019-03-25

Publish Date

2019-12-01

Page Start

2,289

Page End

2,301

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_32497.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=32497

Order

10

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Flow ability Enhancement of Waxy Crude Oil Using New Spirocompound based on Aromatic Amine System

Details

Type

Article

Created At

22 Jan 2023