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28473

Removal Comparative Study for Cd(II) Ions from Polluted Solutions by Adsorption and Coagulation Techniques Using Moringa Oleifera Seeds

Article

Last updated: 22 Jan 2023

Subjects

-

Tags

Physical chemistry

Abstract

The Moringa oleifera seed (MOS) was characterized by pHzpc, Fourier transform infrared spectroscopy (FT-IR), X-ray and scanning electron microscopy (SEM) in order to get an insight of the surface charge, functional groups, and morphology of the biosorbent, respectively. The MOS studies were conducted on Cd (II) with different parameters, such as solution pH, contact time, initial concentration of the pollutant and temperature were examined. Experimental results revealed an increase of the removal percentage of Cd (II) using adsorption compared with coagulation technique with increases of the initial Cd (II) concentration and contact time. However, an opposite trend was observed with an increase of the solution temperature and solution pHs value. The Freundlich isotherm linear equation are better described for the adsorption process and coagulation process for the removal of Cd (II) ions. By Comparing the thermodynamic parameters of Cd (II) removal, such as ∆H, ∆S and ∆G, distinct behaviours were observed, where adsorption process is positive values along all temperatures while coagulation process showed negative values (with exception of -∆G at 277 K). According to S* value, the adsorbent system are very high while the coagulation system are very low
Keywords; Moringa Oleifera seeds, Cd (II), Adsorption, Thermodynamics.

DOI

10.21608/ejchem.2019.6801.1568

Keywords

Keywords, Moringa Oleifera seeds, Cd (II), Adsorption, Thermodynamics

Authors

First Name

A. A.

Last Name

Swelam

MiddleName

-

Affiliation

Faculty of Science, Physical Chemistry Dept. Al Azhar University, Egypt.

Email

abdelsamihswelam@yahoo.com

City

-

Orcid

-

First Name

sheref

Last Name

saied

MiddleName

-

Affiliation

Medicinal and Aromatic Dept. Horti. Res. Institute, A. R. C., Egypt.

Email

sherif_saied_saleh@yahoo.com

City

-

Orcid

-

First Name

Ahmed

Last Name

hafez

MiddleName

-

Affiliation

Faculty of Science, Physical Chemistry Dept. Al Azhar University, Egypt.

Email

a7med_el3med@yahoo.com

City

giza

Orcid

-

Volume

62

Article Issue

8

Related Issue

6668

Issue Date

2019-08-01

Receive Date

2018-12-22

Publish Date

2019-08-01

Page Start

1,499

Page End

1,517

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_28473.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=28473

Order

12

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

-

Details

Type

Article

Created At

22 Jan 2023