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32173

Frequency Modulation of the Raman Spectrum at The Interface DNA - ZrO2 Nanoparticles

Article

Last updated: 22 Jan 2023

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Tags

Inorganic chemistry

Abstract

The development of modern bio-nanoelectronic technologies requires new hybrid organo-inorganic systems that have a specific functional purpose and allow work in the tissues of living organisms. The practical realization and scientific study of a hybrid two-component system in the form of DNA molecule fragments and nanoparticles of biocompatible ceramics was the goal of this work.
The interaction of a DNA molecule with nanoparticles of a solid solution of the composition ZrO2–3mol% Y2O3 (YSZ) was studied using Raman scattering and transmission electron microscopy. Samples of YSZ oxide and hydroxide were investigated in triplicate at room temperature using LabRAM HR Evolution Horiba spectrometer and JEM 200A instrument.
The effect of the force field of the surface of YSZ nanoparticles on the optical properties of the DNA molecule in the TRIS buffer solution was shown. The effects of increasing the intensity of spectral lines in the long-wavelength region 250 – 660 cm-1 (254 cm -1, 322 cm -1, 470 cm -1, 663 cm -1). suppressing the intensity of spectral lines in the shortwave region 600 – 3300 cm -1 (604 cm -1, 917 cm -1, 951 cm -1, 1256 cm -1, 1302 cm -1, 2767 cm -1, 3180 cm -1, 3241 cm -1, 3285 cm -1), as well as shifting lines 519 cm -1, 917 cm -1, 1048 cm -1, 1547 cm -1 and 1639 on 40-60 cm-1 in the shortwave region are established.
From the standpoint of the theory of wave processes, a qualitative description of the detected Up-conversion effect was done. An assumption about the potential applicability of the YSZ nanoparticle surface – DNA nucleotide interfaces as a heterodyne frequency converter in molecular- and bio-electronic devices was made.

DOI

10.21608/ejchem.2019.12898.1806

Keywords

DNA, Semiconductors, Raman scattering, heterodyne transfer of a frequency band, molecular electronics, bio-electronic, powder nanotechnologies

Authors

First Name

A.S.

Last Name

Doroshkevich

MiddleName

-

Affiliation

Joint Institute for Nuclear Research, Dubna, Russia, Donetsk Institute for Physics and Engineering named after O.O. Galkin, Kiev, Ukraine

Email

doroh@jinr.ru

City

-

Orcid

-

First Name

A.A.

Last Name

Nabiev

MiddleName

-

Affiliation

Joint Institute for Nuclear Research, Dubna, Russia, 3ANAS Institute of Radiation Problems, Baku, Azerbaijan

Email

-

City

-

Orcid

-

First Name

A.V.

Last Name

Shylo

MiddleName

-

Affiliation

Donetsk Institute for Physics and Engineering named after O.O. Galkin, Kiev, Ukraine

Email

-

City

-

Orcid

-

First Name

A.

Last Name

Pawlukojć

MiddleName

-

Affiliation

Institute of Nuclear Chemistry and Technology, Warsaw, Poland

Email

-

City

-

Orcid

-

First Name

V.S.

Last Name

Doroshkevich

MiddleName

-

Affiliation

Donetsk National University, Ukraine

Email

-

City

-

Orcid

-

First Name

V.A.

Last Name

Glazunova

MiddleName

-

Affiliation

Donetsk Institute for Physics and Engineering named after O.O. Galkin

Email

-

City

-

Orcid

-

First Name

T.Yu.

Last Name

Zelenyak

MiddleName

-

Affiliation

Tajik technical University named after academician M. S. Оsimi, Dushanbe, Tajikistan

Email

-

City

-

Orcid

-

First Name

N.V.

Last Name

Doroshkevich

MiddleName

-

Affiliation

Joint Institute for Nuclear Research, Dubna, Russia

Email

-

City

-

Orcid

-

First Name

Kh.R.

Last Name

Rahmonov

MiddleName

-

Affiliation

Joint Institute for Nuclear Research, Dubna, Russia

Email

-

City

-

Orcid

-

First Name

E.Kh.

Last Name

Khamzin

MiddleName

-

Affiliation

Joint Institute for Nuclear Research, Dubna, Russia

Email

-

City

-

Orcid

-

First Name

D.D.

Last Name

Nematov

MiddleName

-

Affiliation

Tajik technical University named after academician M. S. Оsimi, Dushanbe, Tajikistan

Email

-

City

-

Orcid

-

First Name

A.S.

Last Name

Burhonzoda

MiddleName

-

Affiliation

Tajik technical University named after academician M. S. Оsimi, Dushanbe, Tajikistan

Email

-

City

-

Orcid

-

First Name

M.A.

Last Name

Khusenov

MiddleName

-

Affiliation

Tajik technical University named after academician M. S. Оsimi, Dushanbe, Tajikistan

Email

-

City

-

Orcid

-

First Name

Kh.T.

Last Name

Kholmurodov

MiddleName

-

Affiliation

Joint Institute for Nuclear Research, Dubna, Russia, Dubna State University, Dubna, Russia

Email

-

City

-

Orcid

-

First Name

S.

Last Name

Majumder

MiddleName

-

Affiliation

Department of Physics National Institute of Technology Patna, India

Email

-

City

-

Orcid

-

First Name

M.

Last Name

Balasoiu

MiddleName

-

Affiliation

Joint Institute for Nuclear Research, Dubna, Russia, Horia Hulubei National Institute for R&D in Physics and Nuclear Engineering, Bucharest, Romania

Email

-

City

-

Orcid

-

First Name

A.

Last Name

Madadzada

MiddleName

-

Affiliation

Joint Institute for Nuclear Research, Dubna, Russia, National Center for Nuclear Research, Baku, Azerbaijan

Email

-

City

-

Orcid

-

First Name

V.I.

Last Name

Bodnarchuk

MiddleName

-

Affiliation

Joint Institute for Nuclear Research, Dubna, Russia

Email

-

City

-

Orcid

-

Volume

62

Article Issue

The First International Conference on Molecular Modeling and Spectroscopy 19-22 February, 2019

Related Issue

5620

Issue Date

2019-07-01

Receive Date

2019-02-28

Publish Date

2019-07-01

Page Start

13

Page End

20

Print ISSN

0449-2285

Online ISSN

2357-0245

Article File

EJCHEM_Volume 62_Issue The First International Conference on Molecular Modeling and Spectroscopy 19-22 February, 2019_Pages 13-20.pdf

PDF . 1.6MB

Link

https://ejchem.journals.ekb.eg/article_32173.html

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https://ejchem.journals.ekb.eg/service?article_code=32173

Order

3

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

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Details

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Article

Created At

22 Jan 2023