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20331

Ultrasonic and Thermal Properties of Bismuth Borotellurite Glasses Doped with NdCl3

Article

Last updated: 22 Jan 2023

Subjects

-

Tags

Physical chemistry

Abstract

Abstract
Bismuth borotellurite glass systems in the form of 65B2O3-12.5TeO2-12.5Bi2O3 - (10-x) Na2O - xNdCl3, x=0, 1, 2, 5, and 10 mole % were melted by traditional method and their amorphous nature were examined by using XRD technique. Densities of the prepared glasses were measured and molar volumes were calculated. The ultrasonic pulse-echo technique at 4 MHz nominal frequency was used to calculate ultrasonic velocities (both of Longitudinal and Shear together). Many of known elastic moduli, such as, longitudinal (L), shear (G), Young (E) and bulk (K) moduli were obtained by using the measured density and ultrasonic velocities. Also Poisson's ratio (σ), the softening temperature (TS), Debye temperature (θD), and microhardness (H) were calculated. The glass transition (Tg) temperature, the crystallization temperature (Tc) and the glass satiability parameters (KSP) could be calculated from the Differential thermal analysis (DTA) that has been carried out in the temperature range from 300 to about 1100 oK for all prepared samples. It is noticed that the mechanical properties (elastic moduli and hardness) of the prepared glass increase with increase of NdCl3%. Also, the softening temperature, the glass transition temperature and stability increase with the increase of NdCl3 % content.

DOI

10.21608/ejchem.2018.5386.1474

Keywords

Borotellurite glasses, ultrasonic velocities, Elastic moduli, Debye Temp, Thermal properties

Authors

First Name

M

Last Name

El-Gazery

MiddleName

-

Affiliation

National Institute of Standards

Email

elgazery_nis@hotmail.com

City

-

Orcid

-

First Name

A.A.

Last Name

Ali

MiddleName

-

Affiliation

Glass Res. Dept., National Res.

Email

ali_nrc@hotmail.com

City

-

Orcid

-

First Name

R

Last Name

El-Mallawany

MiddleName

-

Affiliation

Phys. Dept., Fac. of Sci., Monoufia University, Egypt,

Email

raoufelmallawany@yahoo.com

City

-

Orcid

-

Volume

62

Article Issue

4

Related Issue

5171

Issue Date

2019-04-01

Receive Date

2018-10-02

Publish Date

2019-04-01

Page Start

655

Page End

664

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_20331.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=20331

Order

7

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

-

Details

Type

Article

Created At

22 Jan 2023