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20330

Electrochemical Impedance Spectroscopy (EIS) and Study of Iron Corrosion Inhibition by Turmeric Roots Extract (TRE) in Hydrochloric Acid Solution

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Electrochemistry

Abstract

TURMERIC Root extract (TRE) was tested as corrosion inhibitor for iron in 0.5 M HCl, using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Scanning electron microscope (SEM), and energy dispersive X-rays (EDX) analysis. The inhibition efficiency raised as in time of immersion rises, but decreases with temperature rise. The Nyquist plots showed that, the charge transfer resistance (Rct) increase, and the double layer capacitance (Cdl) decreases with time of immersion increase. Tafel results exhibit that both corrosion current and with corrosion speed are reduced with time of immersion. All impedance spectra of EIS tests exhibit one capacitive loop which indicates that the corrosion reaction is controlled by charge transfer process. IE (%) increases with the concentration of the inhibitor reaching its maximum value, 88. 90%, at 8g/100ml. Thermodynamics parameters: Ea, ΔH*, ΔS* were estimated, and mechanism of corrosion and inhibition was discussed. The adsorption of (TRE) followed Langmuir adsorption isotherm.

DOI

10.21608/ejchem.2018.5295.1476

Keywords

Key words: Iron, Electrochemical Impedance Spectroscopy (EIS), Turmeric Root extract (TRE), double layer capacitance (Cdl), Scanning Electron Microscope (SEM)

Authors

First Name

Kholod

Last Name

Almzarzie

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science, Damascus University, Syria.

Email

kholod.m990@gmail.com

City

-

Orcid

-

First Name

Ahmad

Last Name

Falah

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science, Damascus University, Syria.

Email

prof_ahmad_falah@hotmail.com

City

-

Orcid

-

First Name

Ayman

Last Name

Massri

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science, Damascus University, Syria.

Email

aymanmasrri@gmail.com

City

-

Orcid

-

First Name

Hassan

Last Name

Kellawi

MiddleName

-

Affiliation

Department of Chemistry, Faculty of Science, Damascus University, Syria.

Email

h.kellawi@hotmail.com

City

-

Orcid

-

Volume

62

Article Issue

3

Related Issue

5055

Issue Date

2019-03-01

Receive Date

2018-10-04

Publish Date

2019-03-01

Page Start

501

Page End

512

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_20330.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=20330

Order

10

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Electrochemical Impedance Spectroscopy (EIS) and Study of Iron Corrosion Inhibition by Turmeric Roots Extract (TRE) in Hydrochloric Acid Solution

Details

Type

Article

Created At

22 Jan 2023