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13449

Review Improvement of Polypropylene Properties by Irradiation/Grafting and Other Modifications

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Textile chemistry

Abstract

In Egypt, at Port-Said there is a great company producing polypropylene chips from propylene gas ( and a catalyst) , a product of petroleum. These are
melt spinning into yarns to produce woven or non - woven fabrics.
Polypropylene (PP) is a cheap fabric, bearing chemical resistance and excellent mechanical properties . PP is hydrophobic in nature , inactive synthetic fabric due to the absence of reactive functional groups in the molecular structure, thus preventing its dyeing For this reason , PP fibers are modified by irradiation methods to form free radical centers onto the surface and graft selected vinyl monomers . Different irradiation techniques are adopted involving plasma discharge, electron beams , ozone , UV, γ- rays and other modifications.
PP is grafted with selected monomers including methacrylate derivatives such as ( 2N -Dimethyl amino ethyl methacrylate ,2N morpholino ethyl methacrylate , 2- ethyl methacrylate phosphoric acid , methyl methacrylate, 2- hydroxy ethyl methacrylate ) acrylic acid , styrene , chloro methyl styrene , vinyl acetate etc...
The different variable factors affecting PP irradiation and grafting reactions are considered such as irradiation dose , storage time of irradiated fabric , monomer concentration , reaction time and temperature . Physical properties of grafted PP are studied for those containing tertiary amino or quaternized groups which improved the increase of moisture regain , melting point and enhancement affinity to dyeing by different classes of dyestuffs. Other important properties improvement include ion exchange capacity electrical conductivity , antistatic, insect repellent activity an antibacterial property . PP containing Ag, Zn, ZnO, TiO2 , Cu2O nano particles are antibacterial fabrics which are used as wound healing dressings.

DOI

10.21608/ejchem.2018.4284.1382

Keywords

: Polypropylene, Irradiation, grafting, antistatic antibacterial, insect repellent and ion -exchanger properties

Authors

First Name

Samiha

Last Name

Gawish

MiddleName

Mahmoud

Affiliation

Textile Research Division, National Research Cetre

Email

smgawish@yahoo.com

City

Cairo

Orcid

0000-0002-3736-6036

First Name

Sayeda

Last Name

Mosleh

MiddleName

El-Sayed

Affiliation

Textile Division ,,National Research Centre, Dokki, Cairo

Email

h.mosleh1959@yahoo.com

City

Cairo

Orcid

000-0002-3252-906x

First Name

Ameera

Last Name

Ramadan

MiddleName

-

Affiliation

Textile Division , National Research Centre ,Dokki, Cairo Egypt

Email

ramadanam2000@yahoo.com

City

Cairo

Orcid

-

Volume

62

Article Issue

1

Related Issue

4134

Issue Date

2019-01-01

Receive Date

2018-07-03

Publish Date

2019-01-01

Page Start

29

Page End

48

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_13449.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=13449

Order

4

Type

Review Articles

Type Code

444

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

Review Improvement of Polypropylene Properties by Irradiation/Grafting and Other Modifications

Details

Type

Article

Created At

22 Jan 2023