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High-Performance of Nanoparticles and Their Effects on The Mechanical, Thermal Stability and UV-Shielding Properties of PMMA Nanocomposites

Article

Last updated: 01 Jan 2025

Subjects

-

Tags

Polymer chemistry

Abstract

The target of this work is to choose a suitable nanoparticle for preparing a highly ultraviolet (UV)-shielding from poly (methylmethacrylate)(PMMA) nanocomposites at low concentration and to decrease the destructive effects of UV radiation. Morphologies of the synthesized nanoparticles were investigated by X-ray diffraction (XRD), scanning and transmission electron microscopy (SEM and TEM). Whereas, pure PMMA and its nanocomposites were characterized by using dynamic mechanical analysis (DMA), tensile testing, UV-visible spectra (T%), and thermogravimetric analysis (TGA). The obtained results showed a good correlation between the tensile properties, DMA and TG analysis depending on the type of nanoparticles used in the PMMA matrix, especially in case of ZrO2 and ZnO. Furthermore, UV-vis spectra were analyzed ranging from 200 nm to 800 nm. It showed that UV radiation is significantly blocked from 100% to 0.2 % in the UV range between 200 nm and 360 nm for pure PMMA and to 0.08 % for PMMA/CeO2 nanocomposite and to 0.01 % for PMMA/CeO2 with various types of nanoparticles. After 360 nm, pure PMMA and PMMA/CeO2 were a little bit affected by UV lights, whereas the PMMA based on different nanoparticles was not affected. This result demonstrates that these nanocomposites could be strongly candidates for the sunscreens or for several fields that related to the UV photodegradation effects.

DOI

10.21608/ejchem.2017.1932.1159

Keywords

Nanoparticles, PMMA nanocomposites, X-Ray Diffraction, UV-visible spectra, Tensile Properties, thermogravimetric analysis

Authors

First Name

Hesham

Last Name

Moustafa

MiddleName

-

Affiliation

Polymer Metrology & Technology Department, National Institute of Standards (NIS), Tersa Street, El Haram, El-Giza, P.O Box 136, Giza 12211, Egypt.

Email

hesham.moustafa21@gmail.com

City

-

Orcid

http://orcid.org/0000-0002-1034-8663

First Name

Darwish

Last Name

Darwish

MiddleName

-

Affiliation

Polymer Metrology & Technology Department, National Institute of Standards (NIS), Tersa Street, El Haram, El-Giza, P.O Box 136, Giza 12211, Egypt.

Email

nadarwish@yahoo.com

City

Cairo

Orcid

-

First Name

Ahmed

Last Name

Youssef

MiddleName

-

Affiliation

Packing and Packaging Materials Department, National Research Centre, 33 El Bohouth St. (former El Tahrir st.), Dokki, Giza, Egypt, P.O. 12622

Email

drahmadyoussef@hotmail.com

City

-

Orcid

-

First Name

Sameh

Last Name

Reda

MiddleName

-

Affiliation

Photometry and Radiometry Department, National Institute of Standards (NIS), Tersa Street, El Haram, El-Giza, P.O Box 136, Giza 12211, Egypt.

Email

egyreda@outlook.com

City

-

Orcid

-

First Name

Abdelaziz

Last Name

El-Wakil

MiddleName

-

Affiliation

Polymer Metrology & Technology Department, National Institute of Standards (NIS), Tersa Street, El Haram, El-Giza, P.O Box 136, Giza 12211, Egypt.

Email

abdelaziz_elwakil@yahoo.com

City

-

Orcid

-

Volume

61

Article Issue

1

Related Issue

936

Issue Date

2018-02-01

Receive Date

2017-10-26

Publish Date

2018-02-01

Page Start

23

Page End

32

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_4439.html

Detail API

https://ejchem.journals.ekb.eg/service?article_code=4439

Order

3

Type

Original Article

Type Code

297

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

MainTitle

High-Performance of Nanoparticles and Their Effects on The Mechanical, Thermal Stability and UV-Shielding Properties of PMMA Nanocomposites

Details

Type

Article

Created At

22 Jan 2023