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1201

Effect of Sm3+ Ions on the Transport and Sublattice Magnetization of Perovskite System

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Last updated: 22 Jan 2023

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Abstract

  PEROVSKITE compounds (La1-xSmx)0.7 Ca0.3MnO3 0 ≤ x ≤ 0.14 …. were prepared using the double sintering ceramic technique. The measurement of the magnetic susceptibility at different temperatures as a function of the magnetic field intensity showed the change of the state from completely ordered to completely disordered state at T C which shifts to lower value by increasing Sm content. The tolerance factor decreases with increasing Sm concentration. Resistivity measurements indicate the disappearance of the related peaks with increasing Sm content. The large increase in the resistivity below 530K is related to the spin transition of Mn3+ ions from high to low state.

DOI

10.21608/ejchem.2010.1201

Keywords

Transport phenomena, Magnetic properties, AC resistivity and Perovskite

Volume

53

Article Issue

1

Related Issue

288

Issue Date

2010-02-01

Receive Date

2009-09-08

Publish Date

2010-03-02

Page Start

1

Page End

15

Print ISSN

0449-2285

Online ISSN

2357-0245

Link

https://ejchem.journals.ekb.eg/article_1201.html

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https://ejchem.journals.ekb.eg/service?article_code=1201

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1

Type Code

292

Publication Type

Journal

Publication Title

Egyptian Journal of Chemistry

Publication Link

https://ejchem.journals.ekb.eg/

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Article

Created At

22 Jan 2023